Aqueous Binder for Nanostructured Carbon Anode Materials for Li-Ion Batteries

被引:10
作者
Lis, Marcelina [1 ]
Chudzik, Krystian [1 ]
Bakierska, Monika [1 ]
Swietoslawski, Michal [1 ]
Gajewska, Marta [2 ]
Rutkowska, Malgorzata [1 ]
Molenda, Marcin [1 ]
机构
[1] Jagiellonian Univ, Fac Chem, PL-30387 Krakow, Poland
[2] AGH Univ Sci & Technol, Acad Ctr Mat & Nanotechnol, PL-30059 Krakow, Poland
关键词
POLYACRYLIC-ACID; HIGH-ENERGY; ELECTRODES; PARTICLES; SYSTEM;
D O I
10.1149/2.0591903jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Water soluble hydrophilic polymer poly-N-vinylformamide (PNVF) has been adopted as new binder for selected anode materials based on nanostructured carbon aerogels (CAGs) derived from different types of starch (rice, maize, potato) as well as for graphite as a reference. The results suggest that PNVF can be promising, fluorine free and volatile organic compounds (VOC) free binder for some anode materials especially when taking into consideration its beneficial properties, cost reduction as well as environmental friendliness. PNVF enhances chemical and physical interactions with tested carbons improving adhesion strength of the created composites and thus capacity retention of the formed electrodes during extensive cycling under high current load. Herein, we show that although the binder is only a small part of the entire electrode composition, it has a huge impact on the properties and efficiency of lithium-ion battery. Thereby, every anode material require properly selected binder for the suitable operation and performance of the cell. (C) The Author(s) 2019. Published by ECS.
引用
收藏
页码:A5354 / A5361
页数:8
相关论文
共 26 条
[1]   Functional starch based carbon aerogels for energy applications [J].
Bakierska, M. ;
Molenda, M. ;
Majda, D. ;
Dziembaj, R. .
11TH INTERNATIONAL SYMPOSIUM ON SYSTEMS WITH FAST IONIC TRANSPORT (ISSFIT 11), 2014, 98 :14-19
[2]  
Bakierska M., 2017, WO, Patent No. 2017153855A1
[3]   Multifunctional Carbon Aerogels Derived by Sol-Gel Process of Natural Polysaccharides of Different Botanical Origin [J].
Bakierska, Monika ;
Chojnacka, Agnieszka ;
Swietoslawski, Michal ;
Natkanski, Piotr ;
Gajewska, Marta ;
Rutkowska, Malgorzata ;
Molenda, Marcin .
MATERIALS, 2017, 10 (11)
[4]  
Brodd RJ, 2002, ADVANCES IN LITHIUM-ION BATTERIES, P267, DOI 10.1007/0-306-47508-1_10
[5]   Unveiling the Roles of Binder in the Mechanical Integrity of Electrodes for Lithium-Ion Batteries [J].
Chen, Jianchao ;
Liu, Jianyong ;
Qi, Yue ;
Sun, Tao ;
Li, Xiaodong .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (09) :A1502-A1509
[6]   A comparative study of polyacrylic acid and poly(vinylidene difluoride) binders for spherical natural graphite/LiFePO4 electrodes and cells [J].
Chong, Jin ;
Xun, Shidi ;
Zheng, Honghe ;
Song, Xiangyun ;
Liu, Gao ;
Ridgway, Paul ;
Wang, Ji Qiang ;
Battaglia, Vincent S. .
JOURNAL OF POWER SOURCES, 2011, 196 (18) :7707-7714
[7]   Small things make a big difference: binder effects on the performance of Li and Na batteries [J].
Chou, Shu-Lei ;
Pan, Yuede ;
Wang, Jia-Zhao ;
Liu, Hua-Kun ;
Dou, Shi-Xue .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (38) :20347-20359
[8]   Hierarchical Structures Based on Two-Dimensional Nanomaterials for Rechargeable Lithium Batteries [J].
Cong, Lina ;
Xie, Haiming ;
Li, Jinghong .
ADVANCED ENERGY MATERIALS, 2017, 7 (12)
[9]   High polar polyacrylonitrile as a potential binder for negative electrodes in lithium ion batteries [J].
Gong, Liyuan ;
Minh Hien Thi Nguyen ;
Oh, Eun-Suok .
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 29 :45-47
[10]   Polymeric materials for lithium-ion cells [J].
John, Bibin ;
Cheruvally, Gouri .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2017, 28 (12) :1528-1538