Palladium-catalyzed asymmetric hydrogenation of simple ketones activated by Bronsted acids

被引：29

作者：

Zhou, Xiao-Yu ^{[1
]}

Wang, Duo-Sheng ^{[2
]}

Bao, Ming ^{[1
]}

Zhou, Yong-Gui ^{[2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 22期

基金：

美国国家科学基金会;

关键词：

Palladium; Asymmetric hydrogenation; Bronsted acid; Simple ketones; HIGHLY ENANTIOSELECTIVE HYDROGENATION; IRIDIUM COMPLEXES; AMINO-ALCOHOLS; QUINOLINES; LIGANDS; RU; ENTRY;

D O I：

10.1016/j.tetlet.2011.03.057

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Homogeneous Pd(OCOCF3)(2)/(R)-C-4-TunePhos has been successfully applied in the asymmetric hydrogenation of simple ketones activated by catalytic amount of Bronsted acid with up to 88% ee. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：2826 / 2829

页数：4

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