Microwave-Assisted Chemoselective Hydrogenation Reactions Incorporating Hydrogen as Reducing Agent

被引：16

作者：

Schmoeger, Christine ^{[1
]}

Gallert, Thomas ^{[1
]}

Stolle, Achim ^{[1
]}

Ondruschka, Bernd ^{[1
]}

Bonrath, Werner ^{[2
]}

机构：

[1] Univ Jena, Inst Tech Chem & Environm Chem, D-07743 Jena, Germany

[2] DSM Nutr Prod, R&D Chem Proc Technol, Basel, Switzerland

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2011年 / 34卷 / 03期

关键词：

Alkyne hydrogenation; Chemoselective hydrogenation; Heterogeneous catalysis; Ionic liquids; Microwave heating; IONIC LIQUID CATALYSTS; ETHENE-RICH STREAMS; SELECTIVE HYDROGENATION; PALLADIUM CATALYSTS; ORGANIC-SYNTHESIS; PART; PD; TRANSFORMATIONS; KINETICS; VITAMINS;

D O I：

10.1002/ceat.201000312

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The use of modern microwave equipment affords an easy and safe handling in the laboratory routine. The described quartz reactor system was tested in different reaction types to show its versatile applications. Various liquid-phase hydrogenations were carried out successfully. The construction of the reactor allows the direct introduction of gases into the reaction mixture so that the reduction can be performed with gaseous hydrogen.

引用

页码：445 / 451

页数：7

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