Air quenching as a reliable technique to obtain colossal dielectric constant with low loss in (In, Nb)-co doped TiO2

被引:8
作者
Shahraki, Mohammad Maleki [1 ]
Mahmoudi, Pezhman [2 ]
Karimi, Asadollah [3 ]
机构
[1] Univ Maragheh, Fac Engn, Dept Mat Engn, Maragheh 5518183111, Iran
[2] Sharif Univ Technol, Dept Mat Sci & Engn, Tehran 113659466, Iran
[3] Univ Maragheh, Fac Engn, Dept Chem Engn, Maragheh 5518183111, Iran
关键词
Ceramics; (In; Nb) co-doped TiO2; Air quenching; Dielectrics; CACU3TI4O12; CERAMICS; NB PLUS; PERMITTIVITY;
D O I
10.1016/j.matlet.2020.127513
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this research, for the first time, the effect of air quenching on the microstructural and electrical properties of (In, Nb) co-doped TiO2 was investigated. The FE-SEM images showed that the air quenching has no effect on microstructure of co-doped TiO2. However, air quenching affected the electrical properties so that the dielectric constant in the frequency of 1 kHz at room temperature sharply enhanced from 21*10(3) to 26*10(4) and the dielectric loss surprisingly decreased from 0.6 to 0.1. This incredible improvement in the dielectric properties is attributed to the electron-pined defect dipoles which has been activated through air quenching. (C) 2020 Elsevier B.V. All rights reserved.
引用
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页数:3
相关论文
共 18 条
[1]   Colossal permittivity in ceramics of TiO2 Co-doped with niobium and trivalent cation [J].
Cheng, Xiaojing ;
Li, Zhenwei ;
Wu, Jiagang .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (11) :5805-5810
[2]   Electrode effects in dielectric spectroscopy measurements on (Nb plus In) co-doped TiO2 [J].
Crandles, D. A. ;
Yee, S. M. M. ;
Savinov, M. ;
Nuzhnyy, D. ;
Petzelt, J. ;
Kamba, S. ;
Prokes, J. .
JOURNAL OF APPLIED PHYSICS, 2016, 119 (15)
[3]  
Hu WB, 2013, NAT MATER, V12, P821, DOI [10.1038/NMAT3691, 10.1038/nmat3691]
[4]   Evidences of grain boundary capacitance effect on the colossal dielectric permittivity in (Nb plus In) co-doped TiO2 ceramics [J].
Li, Jinglei ;
Li, Fei ;
Li, Chao ;
Yang, Guang ;
Xu, Zhuo ;
Zhang, Shujun .
SCIENTIFIC REPORTS, 2015, 5
[5]   Microstructure and dielectric properties of (Nb plus In) co-doped rutile TiO2 ceramics [J].
Li, Jinglei ;
Li, Fei ;
Zhuang, Yongyong ;
Jin, Li ;
Wang, Linghang ;
Wei, Xiaoyong ;
Xu, Zhuo ;
Zhang, Shujun .
JOURNAL OF APPLIED PHYSICS, 2014, 116 (07)
[6]   Large reduction of dielectric losses of CaCu3Ti4O12 ceramics via air quenching [J].
Li, Wang ;
Tang, Lu ;
Xue, Fei ;
Xin, Zengnian ;
Luo, Zhe ;
Du, Guoping .
CERAMICS INTERNATIONAL, 2017, 43 (08) :6618-6621
[7]   Polaron relaxation and non-ohmic behavior in CaCu3Ti4O12 ceramics with different cooling methods [J].
Liu, Laijun ;
Shi, Danping ;
Zheng, Shaoying ;
Huang, Yanmin ;
Wu, ShuangShuang ;
Li, Yunhua ;
Fang, Liang ;
Hu, Changzheng .
MATERIALS CHEMISTRY AND PHYSICS, 2013, 139 (2-3) :844-850
[8]   Surface barrier layer effect in (In plus Nb) co-doped TiO2 ceramics: An alternative route to design low dielectric loss [J].
Nachaithong, Theeranuch ;
Kidkhunthod, Pinit ;
Thongbai, Prasit ;
Maensiri, Santi .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2017, 100 (04) :1452-1459
[9]   Surface layer characterizations and sintering time effect on electrical and giant dielectric properties of (In0.05Nb0.05)Ti0.9O2 ceramics [J].
Siriya, Porntip ;
Tuichai, Wattana ;
Danwittayakul, Supamas ;
Chanlek, Narong ;
Thongbai, Prasit .
CERAMICS INTERNATIONAL, 2018, 44 (06) :7234-7239
[10]   Dielectric properties of ( Bi0.5Nb0.5)xTi1-xO2 ceramics with colossal permittivity [J].
Song, Yuechan ;
Liu, Peng ;
Zhao, Xiaogang ;
Guo, Baochun ;
Cui, Xiulei .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 722 :676-682