Preparation and Photocatalysis of CuO/Bentonite Based on Adsorption and Photocatalytic Activity

被引:13
作者
Yang, Cuina [1 ,2 ]
Xu, Hongfa [1 ]
Shi, Jicun [2 ]
Liu, Zhifeng [3 ]
Zhao, Lei [2 ]
机构
[1] Army Engn Univ PLA, State Key Lab Disaster Prevent & Mitigat Explos &, Nanjing 210007, Jiangsu, Peoples R China
[2] Xinxiang Univ, Sch Civil Engn & Architecture, Xinxiang 453003, Henan, Peoples R China
[3] Tianjin Chengjian Univ, Sch Mat Sci & Engn, Tianjin 300384, Peoples R China
关键词
CuO; bentonite; CuO/bentonite composite; adsorption; photocatalysis; METHYLENE-BLUE; DEGRADATION; BENTONITE; PHOTODECOLORIZATION; NANOCOMPOSITE; DECOMPOSITION; ENHANCEMENT; FABRICATION; NANOWIRES; KINETICS;
D O I
10.3390/ma14195803
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A CuO/bentonite composite photocatalyst was prepared to fully utilize the adsorption capacity of bentonite and the photocatalytic activity of CuO. CuO and bentonite were chosen as a photocatalyst due to the excellent optical property of CuO and large specific surface area of bentonite, together with their high stability and low production cost. The sample was characterized by XRD, SEM, and BET. The effects of several factors on degradation process were investigated such as dosage of H2O2, irradiation time, pH of the solution, and dosage of catalyst. The optimum conditions for decolorization of methylene blue solution by CuO/bentonite were determined. Under optimal conditions, the decolorization efficiency of methylene blue by a 1.4% CuO/bentonite (400 & DEG;C) composite photocatalyst under visible irradiation at 240 min reached 96.98%. The degradation process follow edpseudo-second-order kinetics. The photocatalytic mechanism is discussed in detail. This composite structure provides a new solution to the cycle and aggregation of the photocatalyst in water.
引用
收藏
页数:15
相关论文
共 50 条
  • [21] Coupling adsorption and solar photocatalysis using CuO/zeolite for amoxicillin removal: Mathematical modeling and optimization study
    Belaissa, Yahia
    Chabane, Ahmed
    Sarrai, Abdelaziz
    Berrabeh, Ismail
    Hentabli, Mohamed
    Trari, Mohamed
    INORGANIC CHEMISTRY COMMUNICATIONS, 2025, 177
  • [22] Removal of Methyl Green by CuO/COF Photocatalysts with Enhanced Adsorption and Photocatalytic Activity
    Wang, Aijuan
    Chen, Xiaping
    Tang, Hanmin
    Huang, Fei
    Yao, Dongmei
    CHEMISTRYSELECT, 2024, 9 (47):
  • [23] Preparation of TiN-TiO2 composite nanoparticles for organic dye adsorption and photocatalysis
    Tsai, Chi-Gang
    Tseng, Wenjea J.
    CERAMICS INTERNATIONAL, 2020, 46 (10) : 14529 - 14535
  • [24] Synthesis and photocatalytic activity of a bentonite/g-C3N4 composite
    Li, Yeping
    Zhan, Jian
    Huang, Liying
    Xu, Hui
    Li, Huaming
    Zhang, Rongxian
    Wu, Shilong
    RSC ADVANCES, 2014, 4 (23) : 11831 - 11839
  • [25] Preparation of CuO/SiO2 and photocatalytic activity by degradation of methylene blue
    Batista, Ana P. L.
    Pereira Carvalho, Hudson Wallace
    Luz, Gustavo H. P.
    Martins, Paulo F. Q.
    Goncalves, Maraisa
    Oliveira, Luiz C. A.
    ENVIRONMENTAL CHEMISTRY LETTERS, 2010, 8 (01) : 63 - 67
  • [26] ZnO-CuO Nanocomposites with Improved Photocatalytic Activity for Environmental and Energy Applications
    Taufique, M. F. N.
    Haque, Ariful
    Karnati, Priyanka
    Ghosh, Kartik
    JOURNAL OF ELECTRONIC MATERIALS, 2018, 47 (11) : 6731 - 6745
  • [27] Connecting theory with experiment to understand the photocatalytic activity of CuO-ZnO heterostructure
    Oliveira, M. C.
    Fonseca, V. S.
    Andrade Neto, N. F.
    Ribeiro, R. A. P.
    Longo, E.
    de Lazaro, S. R.
    Motta, F., V
    Bomio, M. R. D.
    CERAMICS INTERNATIONAL, 2020, 46 (07) : 9446 - 9454
  • [28] The Ultrahigh Adsorption Capacity and Excellent Photocatalytic Degradation Activity of Mesoporous CuO with Novel Architecture
    Ni, Jing
    Lei, Jianfei
    Wang, Zhaowu
    Huang, Lanlan
    Zhu, Hang
    Liu, Hai
    Hu, Fuqiang
    Qu, Ting
    Yang, Huiyu
    Yang, Haiyang
    Gong, Chunli
    NANOMATERIALS, 2023, 13 (01)
  • [29] Formation of CuO on TiO2 Surface Using its Photocatalytic Activity
    Nishikiori, Hiromasa
    Harata, Naoya
    Yamaguchi, Saho
    Ishikawa, Takashi
    Kondo, Hayato
    Kikuchi, Ayaka
    Yamakami, Tomohiko
    Teshima, Katsuya
    CATALYSTS, 2019, 9 (04)
  • [30] Removal of Cadmium from Aqueous Solution by Nano Composites of Bentonite /TiO2 and Bentonite/ZnO Using Photocatalysis Adsorption Process
    Hossein Abbasi
    Farhad Salimi
    Farhad Golmohammadi
    Silicon, 2020, 12 : 2721 - 2731