Structure of Zn3P2

被引：30

作者：

Zanin, IE ^{[1
]}

Aleinikova, KB

Afanasiev, MM

Antipin, MY

机构：

[1] Voronezh State Univ, Voronezh 394693, Russia

[2] Russian Acad Sci, Inst Organoelement Cpds, Moscow 117901, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 45卷 / 05期

关键词：

structure; zinc phosphide; interatomic distances; bond angles; close packings; tetrahedral voids; equivalent models;

D O I：

10.1007/s10947-005-0067-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of Zn3P2 (P4(2)/nmc, a = b = 8.0785 angstrom, c = 11.3966 angstrom) was solved and refined to R 3.2% in a precision X-ray diffraction experiment (lambda-MoK alpha, graphite monochromator on a primary beam, 27,496 reflections). Interatomic distances and bond angles have been determined. The fcc lattice of the structure is built from phosphorus atoms, and the zinc atoms occupy 3/4 of all tetrahedral voids; the structure is described by two equivalent models where 1/4 occupied (by zinc atoms) and 1/4 vacant voids change places. The zinc atoms that occupy the voids following the diamond principle do not change places.

引用

页码：844 / 848

页数：5