A new NMR chiral derivatizing reagent for determining the absolute configurations of carboxylic acids

被引：23

作者：

Fukushi, Y

Shigematsu, K

Mizutani, J

Tahara, S

机构：

[1] Department of Applied Bioscience, Faculty of Agriculture, Hokkaido University, Sapporo 060, Kita-ku

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 27期

关键词：

D O I：

10.1016/0040-4039(96)00954-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Axially chiral 1,1'-binaphthalene-8,8'-diol (BNDO) was used as a chiral derivatizing reagent to determine the absolute configurations of alpha-chiral carboxylic acids by H-1 and C-13 NMR spectroscopy. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4737 / 4740

页数：4

共 16 条

[1] HOST GUEST COMPLEXATION .33. SEARCH FOR NEW CHIRAL HOSTS [J].

ARTZ, SP ;

DEGRANDPRE, MP ;

CRAM, DJ .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (09) :1486-1496

[2] A WIDELY APPLICABLE METHOD OF RESOLUTION OF BINAPHTHYLS - PREPARATION OF ENANTIOMERICALLY PURE 1,1'-BINAPHTHALENE-2,2'-DIOL, 1,1'-BINAPHTHALENE-2,2'-DITHIOL, 2'-MERCAPTO-1,1'-BINAPHTHALENE-2-OL, AND 1,1'-BINAPHTHALENE-8,8'-DIOL [J].

FABBRI, D ;

DELOGU, G ;

DELUCCHI, O .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (20) :6599-6601

[3] ENANTIOSELECTIVE PROTONATION OF ENOLATES - NOVEL CHIRAL PROTON SOURCES AND REMARKABLE EFFECTS OF THE COUNTERCATION [J].

FUJI, K ;

KAWABATA, T ;

KURODA, A ;

TAGA, T .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (07) :1914-1915

[4] NOE CORRELATIONS IN MTPA, MNCB AND MBNC ESTERS [J].

FUKUSHI, Y ;

YAJIMA, C ;

MIZUTANI, J .

TETRAHEDRON LETTERS, 1994, 35 (50) :9417-9420

[5] PRELACINAN-7-OL, A NOVEL SESQUITERPENE FROM RUDBECKIA-LACINIATA [J].

FUKUSHI, Y ;

YAJIMA, C ;

MIZUTANI, J .

TETRAHEDRON LETTERS, 1994, 35 (47) :8809-8812

[6] A NEW METHOD FOR ESTABLISHMENT OF ABSOLUTE-CONFIGURATIONS OF SECONDARY ALCOHOLS BY NMR-SPECTROSCOPY [J].

FUKUSHI, Y ;

YAJIMA, C ;

MIZUTANI, J .

TETRAHEDRON LETTERS, 1994, 35 (04) :599-602

[7] NEW CHIRAL ANISOTROPIC REAGENTS, NMR TOOLS TO ELUCIDATE THE ABSOLUTE-CONFIGURATIONS OF LONG-CHAIN ORGANIC-COMPOUNDS [J].

KUSUMI, T ;

TAKAHASHI, H ;

XU, P ;

FUKUSHIMA, T ;

ASAKAWA, Y ;

HASHIMOTO, T ;

KAN, Y ;

INOUYE, Y .

TETRAHEDRON LETTERS, 1994, 35 (25) :4397-4400

[8] CONFORMATIONAL STRUCTURE AND DYNAMICS OF ARYLMETHOXYACETATES - DNMR SPECTROSCOPY AND AROMATIC SHIELDING EFFECT [J].

LATYPOV, SK ;

SECO, JM ;

QUINOA, E ;

RIGUERA, R .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (03) :504-515

[9] DETERMINATION OF THE ABSOLUTE STEREOCHEMISTRY OF CHIRAL AMINES BY H-1-NMR OF ARYLMETHOXYACETIC ACID-AMIDES - THE CONFORMATIONAL MODEL [J].

LATYPOV, SK ;

SECO, JM ;

QUINOA, E ;

RIGUERA, R .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (06) :1538-1545

[10] OPTICAL RESOLUTION OF 2'-METHOXY-1,1'-BINAPHTHYL-2-CARBOXYLIC ACID, AND APPLICATION TO CHIRAL DERIVATIZING AGENT FOR HPLC SEPARATION OF ENANTIOMERIC ALCOHOLS AND AMINES [J].

MIYANO, S ;

OKADA, S ;

HOTTA, H ;

TAKEDA, M ;

KABUTO, C ;

HASHIMOTO, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) :1528-1533

← 1 2 →