Electrochemical reduction of CO2 in microspores

被引:9
|
作者
Yamamoto, T
Hirota, K
Tryk, DA
Hashimoto, K
Fujishima, A
Okawa, M
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
[2] Univ Tokyo, Adv Sci & Technol Res Ctr, Meguro Ku, Tokyo 1538904, Japan
[3] Elect Power Dev Co Ltd, Chuo Ku, Tokyo 1048165, Japan
关键词
D O I
10.1246/cl.1998.825
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CO2 electroreduction was examined on high area nickel electrocatalysts supported on activated carbon fibers, which contain slit-shaped pores with widths on the order of nanometers. The current efficiency for CO2 reduction to CO reached values of 70%. In contrast, much smaller amounts of CO were generated for the same type of high area nickel catalyst supported on non-activated carbon fibers. The enhancement of the CO2 reduction selectivity with the microporous support is thought to include a nanospace effect, which gives rise to high pleasure-like effects at ambient pressure.
引用
收藏
页码:825 / 826
页数:2
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