Separation of isomeric cereal-derived arabinoxylan-oligosaccharides by collision induced dissociation-travelling wave ion mobility spectrometry-tandem mass spectrometry (CID-TWIMS-MS/MS)

被引：9

作者：

Juvonen, Minna ^{[1
]}

Bakx, Edwin ^{[2
]}

Schols, Henk ^{[2
]}

Tenkanen, Maija ^{[1
]}

机构：

[1] Univ Helsinki, Dept Food & Nutr, POB 66, Helsinki 00014, Finland

[2] Wageningen Univ & Res, Lab Food Chem, Bornse Weilanden 9, NL-6708 WG Wageningen, Netherlands

来源：

FOOD CHEMISTRY | 2022年 / 366卷

关键词：

Arabinoxylan; Oligosaccharides; Ion mobility spectrometry; Tandem mass spectrometry; STRUCTURAL-ANALYSIS; CROSS-SECTIONS; PART; IDENTIFICATION; DISACCHARIDES; LINKAGE; DIFFERENTIATION; FRAGMENTATION; SPECTRA; ANOMERS;

D O I：

10.1016/j.foodchem.2021.130544

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The potential of travelling wave ion mobility spectroscopy in combination with collision induced dissociation tandem mass spectrometry (CID-TWIMS-MS/MS) to separate cereal-derived isomeric arabinoxylanoligosaccharides (A)XOS was investigated. Three trisaccharide, four tetrasaccharide, and four pentasaccharide (A)XOS isomers were analyzed by positive and negative ionization TWIMS-MS and CID-TWIMS-MS/MS. The triand pentasaccharide isomers were distinguishable by the ATDs of the precursor ions. The CID-TWIMS-MS/MS could separate most of the isomeric fragment ions produced from tetra- and pentasaccharide (A)XOS. Finally, the base peak mobility spectrum is introduced as a practical tool for (A)XOS fingerprinting.

引用

页数：9

共 5 条

[1] Peak width-mass correlation in CID MS/MS of isomeric oligosaccharides using traveling-wave ion mobility mass spectrometry
Yamagaki, Tohru
Sato, Akihiro
JOURNAL OF MASS SPECTROMETRY, 2009, 44 (10): : 1509 - 1517
[2] Isomeric Oligosaccharides Analyses Using Negative-ion Electrospray Ionization Ion Mobility Spectrometry Combined with Collision-induced Dissociation MS/MS
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ANALYTICAL SCIENCES, 2009, 25 (08) : 985 - 988
[3] Structural Analysis of a Heteropolysaccharide from Saccharina japonica by Electrospray Mass Spectrometry in Tandem with Collision-Induced Dissociation Tandem Mass Spectrometry (ESI-CID-MS/MS)
Jin, Weihua
Wang, Jing
Ren, Sumei
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MARINE DRUGS, 2012, 10 (10) : 2138 - 2152
[4] Assessment of the similarity between in-source collision-induced dissociation (IS-CID) fragment ion spectra and tandem mass spectrometry (MS/MS) product ion spectra for seized drug identifications
Sharp, Jared
Do, Daniel
Davidson, Tyler
FORENSIC CHEMISTRY, 2022, 30
[5] Positive and negative electrospray ionisation travelling wave ion mobility mass spectrometry and low-energy collision-induced dissociation of sialic acid derivatives
Winkler, Wolfgang
Huber, Wolfgang
Vlasak, Reinhard
Allmaier, Guenter
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2011, 25 (21) : 3235 - 3244

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