Tetra-μ-acetato-bis{[2-(chloromethyl)pyridine]copper(II)}

被引：2

作者：

Zhang, Shi-Guo

Liu, Qi-Sheng

Shi, Jing-Min ^{[1
]}

机构：

[1] Binzhou Univ, Inst Mat Chem, Dept Chem & Chem Engn, Binzhou 256603, Peoples R China

[2] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807032321

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecule of the title compound, [Cu-2(C2H3O2)(4)- (C6H6ClN)(2)], lies on an inversion center and the Cu atom has a square-pyramidal CuO4N geometry. The four acetate groups act as bridging ligands.

引用

页码：M2082 / U545

页数：8

共 9 条

[1]

BRUKER, 1997, SMART VERSION 5 6A S

[2]

BRUKER, 2001, SHELXTL VERSION 6 12

[3] STRUCTURE AND MAGNETISM OF BIS(2-CHLOROPYRIDINE)TETRAKIS(MU-TRICHLOROACETATO(O,O'))-DICOPPER(II) - INFLUENCE OF BRIDGING LIGAND ON MAGNETIC-PROPERTIES OF DIMERIC COPPER(II) CARBOXYLATE ADDUCTS [J].

MORELAND, JA ;

DOEDENS, RJ .

INORGANIC CHEMISTRY, 1978, 17 (03) :674-679

[4] MOLECULAR-STRUCTURE AND MAGNETIC-PROPERTIES OF ACETATO-BRIDGED LANTHANIDE(III) DIMERS [J].

PANAGIOTOPOULOS, A ;

ZAFIROPOULOS, TF ;

PERLEPES, SP ;

BAKALBASSIS, E ;

MASSONRAMADE, I ;

KAHN, O ;

TERZIS, A ;

RAPTOPOULOU, CP .

INORGANIC CHEMISTRY, 1995, 34 (19) :4918-4920

[5]

Sheldrick G.M., 1996, SADABS VERSION 2008

[6] A MIXED-VALENT POLYIRON OXO COMPLEX THAT MODELS THE BIOMINERALIZATION OF THE FERRITIN CORE [J].

TAFT, KL ;

PAPAEFTHYMIOU, GC ;

LIPPARD, SJ .

SCIENCE, 1993, 259 (5099) :1302-1305

[7] Octanuclearity in copper(II) chemistry: Preparation, characterization, and magnetochemistry of [Cu-8(dpk center dot OH)(8)(O2CCH3)(4)](ClO4)(4)center dot 9H(2)O (dpk center dot H2O equals the hydrated, gem-diol form of Di-2-pyridyi ketone) [J].

Tangoulis, V ;

Raptopoulou, CP ;

Terzis, A ;

Paschalidou, S ;

Perlepes, SP ;

Bakalbassis, EG .

INORGANIC CHEMISTRY, 1997, 36 (18) :3996-4006

[8] The [Cu-2(O2CMe)(4)(H2O)(2)]/(py)(2)CO system as the source of an unusual heptanuclear complex and a novel dodecanuclear ''Flywheel'' cluster [J].

Tangoulis, V ;

Raptopoulou, CP ;

Paschalidou, S ;

Bakalbassis, EG ;

Perlepes, SP ;

Terzis, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (10) :1083-1085

[9] An octanuclear copper(II) complex containing the gem-diol anionic form of di-2-pyridyl ketone (dpd-2H) and 2-hydroxypyridine:: Synthesis, crystal structure, and properties of [Cu8(dpd-2H)4(μ2-O2CMe)4{2-(OH)C5H4N}4]-(ClO4)4•4H2O [J].

Tong, ML ;

Lee, HK ;

Tong, YX ;

Chen, XM ;

Mak, TCW .

INORGANIC CHEMISTRY, 2000, 39 (20) :4666-4669

← 1 →