Metal-Organic Framework Isomers with Diamondoid Networks Constructed of a Semirigid Tetrahedral Linker

被引：33
|
作者：
Tian, Jian [1 ]
Motkuri, Radha Kishan [1 ]
Thallapally, Praveen K. [1 ]
McGrail, B. Peter [1 ]
机构：
[1] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA
来源：
CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 12期
关键词：
SECONDARY BUILDING UNITS; SEPARATION APPLICATIONS; COORDINATION POLYMERS; GAS-ADSORPTION; SINGLE-CRYSTAL; CARBON-DIOXIDE; CHEMISTRY; DESIGN; CATENATION; MAGNETISM;
D O I：
10.1021/cg101222w
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvothermal assembly of a semirigid tetrahedral carboxylate ligand tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H4X) with Cd(II) ion in different solvent systems yields three novel metal-organic framework isomers (1-3) based on different secondary building units (SBUs) Although all three frameworks have the same dia (diamondoid) topology, complexes 1 and 3 are noncentrosymmetric and complex 2 is centrosymmetric One of the networks (1) shows cross-linked 3-fold interpenetration of the single dia net and exhibits permanent porosities, as confirmed by Brunauer-Emmett-Teller (BET) and selective CO2 adsorption
引用
收藏
页码：5327 / 5333
页数：7
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