Metal-Organic Framework Isomers with Diamondoid Networks Constructed of a Semirigid Tetrahedral Linker

被引：33

作者：

Tian, Jian ^{[1
]}

Motkuri, Radha Kishan ^{[1
]}

Thallapally, Praveen K. ^{[1
]}

McGrail, B. Peter ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99352 USA

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 12期

关键词：

SECONDARY BUILDING UNITS; SEPARATION APPLICATIONS; COORDINATION POLYMERS; GAS-ADSORPTION; SINGLE-CRYSTAL; CARBON-DIOXIDE; CHEMISTRY; DESIGN; CATENATION; MAGNETISM;

D O I：

10.1021/cg101222w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvothermal assembly of a semirigid tetrahedral carboxylate ligand tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H4X) with Cd(II) ion in different solvent systems yields three novel metal-organic framework isomers (1-3) based on different secondary building units (SBUs) Although all three frameworks have the same dia (diamondoid) topology, complexes 1 and 3 are noncentrosymmetric and complex 2 is centrosymmetric One of the networks (1) shows cross-linked 3-fold interpenetration of the single dia net and exhibits permanent porosities, as confirmed by Brunauer-Emmett-Teller (BET) and selective CO2 adsorption

引用

页码：5327 / 5333

页数：7

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