Highly enantioselective allylation of arylaldehydes catalyzed by a silver(I)-chiral binaphthylthiophosphoramide

被引：25

作者：

Wang, CJ ^{[1
]}

Shi, M ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 15期

关键词：

allylation; N; S ligands; silver; asymmetric catalysis; aldehydes;

D O I：

10.1002/ejoc.200300099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Chiral diphenylthiophosphoramide L2 prepared from diphenylthiophosphinic chloride and (R)-(+)-N-ethyl-1,1'-binaphthyl-2,2'-diamine 2 was used as a Catalytic chiral ligand in the silver(1)-catalyzed enantioselective allylation reaction of arylaldehydes with allyltributyltin to furnish high ee (up to 98%) of the homoallylic alcohols. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

引用

页码：2823 / 2828

页数：6

共 27 条

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