50 Years of adventures with neutron activation analysis with the special emphasis on radiochemical separations

被引：5

作者：

Dybczynski, Rajmund S. ^{[1
]}

机构：

[1] Inst Nucl Chem & Technol, Lab Nucl Analyt Tech, PL-03195 Warsaw, Poland

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2015年 / 303卷 / 02期

关键词：

NAA; Radiochemical separations; Definitive methods; Ratio primary reference measurement procedures (RPRMPs); Quality assurance; Reference materials; INORGANIC TRACE ANALYSIS; ION-EXCHANGE-RESIN; RARE-EARTH COMPLEXES; IRRADIATED BIOLOGICAL-MATERIALS; CERTIFIED REFERENCE MATERIALS; DETERMINING CHEMICAL YIELD; HYDROBROMIC ACID-MEDIUM; ANION-EXCHANGE; EXTRACTION CHROMATOGRAPHY; SELECTIVE SEPARATION;

D O I：

10.1007/s10967-014-3822-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Author's activity in the field of neutron activation analysis (NAA) over the past 50 years is reviewed and the changing role of radiochemical separations in NAA is discussed. Two philosophies which have existed in this area are reminded and their evolution in time is described. New ion exchange systems for the separation of trace elements were devised and the role of NAA in certification of reference materials is highlighted. The idea of definitive methods by RNAA (now named: ratio primary reference measurement procedures, RPRMPs) is presented and illustrated by several examples. The role of RPRMPs in quality assurance in inorganic trace analysis is emphasized.

引用

页码：1067 / 1090

页数：24

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