Oxidative kinetic resolution of racemic secondary alcohols catalyzed by resin supported sulfonato-Mn(salen) complex in water

被引：37

作者：

Kantam, M. Lakshmi ^{[1
]}

Ramani, T. ^{[1
]}

Chakrapani, L. ^{[1
]}

Choudary, B. M. ^{[1
]}

机构：

[1] Ogene Syst, Hyderabad 500037, Andhra Pradesh, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2007年 / 274卷 / 1-2期

关键词：

kinetic resolution; sulfonato-Mn(saten); complex; (R; R)-1; resin; PhI(OAc)(2); enantioselectivity (ee);

D O I：

10.1016/j.molcata.2007.04.020

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative kinetic resolution of racemic secondary alcohols catalyzed by resin supported sulfonato-Mn(salen) complex (R,R)-1 with good to excellent ee's in water in the presence of diacetoxyiodobenzene (PhI(OAC)(2)) is described. The resin supported (R,R)-1 was recovered quantitatively by simple filtration and reused for three times with consistent activity. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：11 / 15

页数：5

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