Recent advances in Co-catalyzed C-C and C-N bond formation via ADC and ATH reactions

被引：13

作者：

Zhang, Meng-Juan ^{[1
,2
]}

Ge, Xiao-Lan ^{[1
]}

Young, David J. ^{[3
]}

Li, Hong-Xi ^{[2
]}

机构：

[1] Bozhou Univ, Tradit Chinese Med Coll, Bozhou 236800, Peoples R China

[2] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Jiangsu, Peoples R China

[3] Charles Darwin Univ, Coll Engn Informat Technol & Environm, Darwin, NT 0909, Australia

来源：

TETRAHEDRON | 2021年 / 93卷

基金：

中国国家自然科学基金;

关键词：

Cobalt catalyst; Auto-transfer-hydrogen; Acceptorless dehydrogenative coupling; C-C bond formation; C-N bond formation; GAMMA-AMINO-ALCOHOLS; BORROWING HYDROGEN; SECONDARY ALCOHOLS; ALPHA-ALKYLATION; SELECTIVE ALKYLATION; ACCEPTORLESS DEHYDROGENATION; FUNCTIONALIZED PYRIDINES; RUTHENIUM CATALYST; UNACTIVATED AMIDES; IRIDIUM CATALYSTS;

D O I：

10.1016/j.tet.2021.132309

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Scarce precious metals commonly adopted for crucial technologies such as catalysis can potentially be replaced with inexpensive, earth-abundant metals. Cobalt is gaining attention in this respect because of its distinctive redox chemistry that is suited to catalyzing the formation of C-C and C-N bonds. Two recently developed examples are cobalt-catalyzed acceptorless dehydrogenative coupling (ADC) and auto-transfer-hydrogenative (ATH) reactions for the reliable and mild construction of these bonds. Ad-vances in both classes of reaction are herein reviewed (2013-present). (c) 2021 Elsevier Ltd. All rights reserved.

引用

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