Design and Redox Function of Conjugated Complexes with Polyanilines or Quinonediimines

Because of their potential application as new electrical materials that depend on their redox properties, pi-conjugated polymers and oligomers have attracted much attention. Polyanilines, which are chemically stable, are one of the promising classes of conducting pi,conjugated polymers. Polyanilines exist in three different discrete redox forms, which include the fully reduced leucoemeraidine, the semioxidized emeraidine, and the fully oxidized pernigraniline base form. The redox-active 1,4-phenylenediamine (PD) and 1,4-benzoquinonediimine, unit molecules of the emeraidine base form, can bind to transition metals to afford novel conjugated complexes. The introduction of metal centers into alpha-conjugated polymers is expected to dramatically change their functions. In this Account, we describe our ongoing research into the construction of conjugated complexes with redox-active pi-conjugated polyanilines and 1,4-benzoquinonediimines. These systems can form architecturally controlled functionallzed systems that depend on their dynamic redox properties, resulting in highly selective and versatile electron-transfer reactions and functionalized materials. Complexation with metals (Pd, V, Cu, etc.) occurred via the two nitrogen atoms of the quinonediimine moiety of the emeraidine base form of poly(o-toluidine) to afford the single-strand or cross-linked network conjugated complexes with d,pi-conjugation. The complexation of the redox-active alpha-conjugated 1,4-benzoquinonedlimines, unit molecules of the emeraidine base form, with palladium(II) compounds yielded a variety of conjugated complexes. Through regulation of the coordination mode of the quinonediimine moiety, we were able to architecturally control the formation of conjugated bimetallic, polymeric, or macrocyclic complexes. Complexation modulated the redox function of the quinonediimine moiety. Introduced metals act as a metallic dopant, and the complexed quinonediimine is stabilized as an electron sink. Furthermore, chirality could be induced into a pi-conjugated backbone through complexation with optically active transition compounds, resulting in chiral d,alpha-conjugated complexes. We could also modulate the functional properties of conjugated complexes based on the redox states of the redox-active pi-conjugated moieties. We also demonstrated how complexes with redox-active pi-conjugated molecules can control the architecture of redox-functionalized systems through the metal imido bonds of these systems. Using the one-pot preparation of (arylimido)vanadium(V) compounds from the corresponding anilines, we synthesized binuclear complexes with axial chirality and trinuclear complexes with a tridendritic centrosymmetric structural motif. Such structures showed a strong tendency to self-assemble.