Photovoltaic Performance of Porphyrin-Based Dye-Sensitized Solar Cells with Binary Ionic Liquid Electrolytes

被引：3

作者：

Khan, Sher Bahadar ^{[1
,2
]}

Yadav, Pankaj Kumar ^{[3
]}

Decoppet, Jean-David ^{[3
]}

Yi, Chenyi ^{[3
]}

Al-Ghamdi, Mohammed S. A. ^{[4
]}

Alhogbi, Basma G. ^{[1
]}

Asiri, Abdullah M. ^{[1
,2
]}

Zakeeruddin, Shaik M. ^{[3
]}

Graetzel, Michael ^{[3
]}

机构：

[1] King Abdulaziz Univ, Fac Sci, Chem Dept, POB 80203, Jeddah 21589, Saudi Arabia

[2] King Abdulaziz Univ, Ctr Excellence Adv Mat Res CEAMR, POB 80203, Jeddah 21589, Saudi Arabia

[3] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

[4] King Abdulaziz Univ, Fac Sci, Phys Dept, Jeddah 21589, Saudi Arabia

来源：

ENERGY TECHNOLOGY | 2020年 / 8卷 / 06期

关键词：

dye-sensitized solar cells; ionic liquid electrolytes; organic dyes; photovoltaics; porphyrin dyes; HIGH-EFFICIENCY;

D O I：

10.1002/ente.202000092

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Herein, green porphyrin sensitizer Y350-based dye-sensitized solar cells (DSCs) with binary ionic liquid-based electrolytes are studied, which are a mixture of 1-methyl-3-propyl-imidazolium iodide and 1-methyl-1-butylpyrrolidinium bis(trifluromethylsulfonyl) -imide, 1-butylpyridinium bis(trifluromethylsulfonyl)imide, 1-methyl-3-ethylimidazolium bis(trifluromethylsulfonyl)imide, or 1-methyl-3-ethylimidazolium tetracyanoborate. The best semitransparent green DSC device exhibits a short-circuit photocurrent density of 9.1 mA cm(-2), an open-circuit photovoltage of 727 mV, and a fill factor of 70%, corresponding to an overall power conversion efficiency (PCE) of 4.9% under standard AM 1.5G illuminations at 100 mW cm(-2). The PCE increases to 6.1% with opaque films containing larger light-scattering TiO2 particles.

引用

页数：5

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