Interaction between 2,4,6-triamino-1,3,5-triazine and alkyl esters of phosphonic and phosphorus acids

被引:8
|
作者
Troev, K [1 ]
Tsevi, R [1 ]
机构
[1] Bulgarian Acad Sci, Inst Polymers, BU-1113 Sofia, Bulgaria
关键词
dialkyl phosphonates; alkyldialkyl phosphonates; trialkyl phosphates; triazine; alkylation;
D O I
10.1080/10426509808032453
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
2,4,6-triamino-1,3,5-triazinealkylammonium alkyl- phosphonates -(C3H6N6R)+-OP(O)(X) (OR) (X=H, CH3; R=CH3; C2H5) and 2,4,6-triamino-1,3,5-triazineammonium dimethyl phosphate were synthesized (X=OCH3; R=CH3). When R=CH3 these salts decompose evolving carbene "CH2" and convert into the corresponding ammonium salts {C3H7N6}+-OP(O)(X)(OR). It has been established that when X=OCH3 and R=CH3 alkylammonium salts quantitatively convert into the corresponding ammonium salts. It has been assumed that the low basicity of the amino groups of the monoalkylated melamine is the reason to obtain only monoalkylated products.
引用
收藏
页码:61 / 68
页数:8
相关论文
共 50 条
  • [11] Synthesis of 2,4,6-triamino-1,3,5-trinitrobenzene
    da Silva, Gilson
    Mattos, Elizabeth da Costa
    JOURNAL OF AEROSPACE TECHNOLOGY AND MANAGEMENT, 2011, 3 (01) : 65 - 72
  • [12] Metallochromic properties of melamine-derived organic reagent N-(2'-thienylmethylene)-2,4,6-triamino-1,3,5-triazine
    Chohan, ZH
    Aminuddin, M
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 1996, 18 (01): : 32 - 34
  • [13] Spectrophotometric determination of cobalt(II) using chromogenic reagent N-(2-pyrrolylmethylene)-2,4,6-triamino-1,3,5-triazine
    Chohan, ZH
    Farooq, MA
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 1998, 20 (01): : 51 - 53
  • [14] Spectrophotometric determination of cobalt(II) using N-(2-pyrrolylmethylene)-2,4,6-triamino-1,3,5-triazine as a chromogenic reagent
    Chohan, ZH
    Farooq, MA
    JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2001, 23 (03): : 168 - 170
  • [15] Persistence of 2,4,6-triamino-1,3,5-trinitrobenzene in the environment
    Christian, Olivia
    Spencer, Michael
    Ladyman, Melissa
    Persico, Federica
    Gutierrez-Carazo, Encina
    Kadansky, Evie
    Temple, Tracey
    ENVIRONMENTAL RESEARCH, 2023, 239
  • [16] INFLUENCE OF AMMONIUM POLYPHOSPHATES AND 2,4,6-TRIAMINO-1,3,5-TRIAZINE ON THE MECHANICAL-PHYSICAL PROPERTIES OF POLYURETHANE AND ALKALI-ACTIVATED MATERIALS
    Music, Branka
    Horvat, Barbara
    6TH INTERNATIONAL CONFERENCE ON TECHNOLOGIES & BUSINESS MODELS FOR CIRCULAR ECONOMY, 2024, : 69 - 91
  • [17] Preparation, crystal structure, vibrational spectral and density functional studies of bis (4-nitrophenol)-2,4,6-triamino-1,3,5-triazine monohydrate
    Kanagathara, N.
    Marchewka, M. K.
    Drozd, M.
    Renganathan, N. G.
    Gunasekaran, S.
    Anbalagan, G.
    JOURNAL OF MOLECULAR STRUCTURE, 2013, 1049 : 345 - 354
  • [18] A kinetic study of a halogenation of few anilides by N2,N4N6-trichloro-2,4,6-triamino-1,3,5-triazine
    Ratnam, K. V.
    Sundar, B. Syama
    Radrakrishnamurti, P. S.
    OXIDATION COMMUNICATIONS, 2008, 31 (02): : 340 - 347
  • [19] INTERACTION OF 1,3,5-TRIETHYLHEXAHYDRO-1,3,5-TRIAZINE WITH TRIMETHYLSILYL ESTERS OF TRIVALENT PHOSPHORUS-ACIDS
    PRISHCHENKO, AA
    LIVANTSOV, MV
    KUSTRYA, DN
    GRIGOREV, EV
    LUZIKOV, YN
    ZHURNAL OBSHCHEI KHIMII, 1994, 64 (09): : 1575 - 1576
  • [20] 2,4,6-Tripiperidino-1,3,5-triazine
    Khan, AA
    Wismach, C
    Jones, PG
    Streubel, R
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1757 - O1758