This paper presents CCD multicolor photometry for the old open cluster NGC 188. The observations were carried out as part of the Beijing-Arizona-Taiwan-Connecticut Multicolor Sky Survey from 1995 February to 2008 March, using 15 intermediate-band filters covering 3000-10000 angstrom. By fitting the Padova theoretical isochrones to our data, the fundamental parameters of this cluster are derived: an age of t = 7.5 +/- 0.5 Gyr, a distance modulus of (m-M)(0) = 11.17 +/- 0.08, and a reddening of E (B-V) = 0.036 +/- 0.010. The radial surface density profile of NGC 188 is obtained using the star count. By fitting the King model, the structural parameters of NGC 188 are derived: a core radius of R-c = 3'.80, a tidal radius of R-t = 44'.78, and a concentration parameter of C-0 = log(R-t/R-c)= 1.07. Fitting the mass function (MF) to a power-law function phi(m) proportional to m(alpha), the slopes of the MFs for different spatial regions are derived. We find that NGC 188 presents a slope break in the MF. The break mass is m(break) = 0.885 M-circle dot. In the mass range above m(break), the slope of the overall region is alpha = -0.76. The slope of the core region is alpha = 1.09, and the slopes of the external regions are alpha = -0.86 and alpha = -2.15, respectively. In the mass range below m(break), these slopes are alpha = 0.12, alpha = 4.91, alpha = 1.33, and alpha = -1.09, respectively. The mass segregation in NGC 188 is reflected in the obvious variation of the slopes in different spatial regions of this cluster.