Quantum-Dot-Sensitized TiO2 Inverse Opals for Photoelectrochemical Hydrogen Generation

被引:213
作者
Cheng, Chuanwei [2 ,3 ]
Karuturi, Siva Krishna [1 ]
Liu, Lijun [1 ]
Liu, Jinping [2 ]
Li, Hongxing [2 ]
Su, Liap Tat [1 ]
Tok, Alfred Iing Yoong [1 ]
Fan, Hong Jin [2 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Nanyang Technol Univ, Sch Phys & Math Sci, Div Phys & Appl Phys, Singapore 637371, Singapore
[3] Tongji Univ, Dept Phys, Shanghai Key Lab Special Artificial Microstruct M, Shanghai 200092, Peoples R China
关键词
hydrogen generation; inverse opals; photoelectrochemical cells; photonic crystals; quantum dots; ATOMIC LAYER DEPOSITION; SEMICONDUCTOR NANOWIRES; PHOTONIC CRYSTALS; SOLAR; NANOTUBE; WATER; NANOSTRUCTURES; FABRICATION; ARRAYS;
D O I
10.1002/smll.201101660
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new nanoarchitecture photoelectrode design comprising CdS quantum-dot-sensitized, optically and electrically active TiO 2 inverse opals is developed for photoelectrochemical water splitting. The photoelectrochemical performance shows high photocurrent density (4.84 mA cm -2 at 0 V vs. Ag/AgCl) under simulated solar-light illumination. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:37 / 42
页数:6
相关论文
共 38 条
[11]   Light Trapping in Silicon Nanowire Solar Cells [J].
Garnett, Erik ;
Yang, Peidong .
NANO LETTERS, 2010, 10 (03) :1082-1087
[12]   Recent Advances in Sensitized Mesoscopic Solar Cells [J].
Graetzel, Michael .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1788-1798
[13]   Sacrificial-layer atomic layer deposition for fabrication of non-close-packed inverse-opal photonic crystals [J].
Graugnard, Elton ;
King, Jeffrey S. ;
Gaillot, Davy P. ;
Summers, Christopher J. .
ADVANCED FUNCTIONAL MATERIALS, 2006, 16 (09) :1187-1196
[14]   Dye-Sensitized Solar Cell Based on a Three-Dimensional Photonic Crystal [J].
Guldin, Stefan ;
Huttner, Sven ;
Kolle, Matthias ;
Welland, Mark E. ;
Mueller-Buschbaum, Peter ;
Friend, Richard H. ;
Steiner, Ullrich ;
Tetreault, Nicolas .
NANO LETTERS, 2010, 10 (07) :2303-2309
[15]   Synergistic Effect of CdSe Quantum Dot Sensitization and Nitrogen Doping of TiO2 Nanostructures for Photoelectrochemical Solar Hydrogen Generation [J].
Hensel, Jennifer ;
Wang, Gongming ;
Li, Yat ;
Zhang, Jin Z. .
NANO LETTERS, 2010, 10 (02) :478-483
[16]   Semiconductor Nanowires for Energy Conversion [J].
Hochbaum, Allon I. ;
Yang, Peidong .
CHEMICAL REVIEWS, 2010, 110 (01) :527-546
[17]   Kinetics of Stop-Flow Atomic Layer Deposition for High Aspect Ratio Template Filling through Photonic Band Gap Measurements [J].
Karuturi, Siva Krishna ;
Liu, Lijun ;
Su, Liap Tat ;
Zhao, Yang ;
Fan, Hong Jin ;
Ge, Xiaochen ;
He, Sailing ;
Yoong, Alfred Tok Iing .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (35) :14843-14848
[18]   Compact Inverse-Opal Electrode Using Non-Aggregated TiO2 Nanoparticles for Dye-Sensitized Solar Cells [J].
Kwak, Eun Sik ;
Lee, Wonmok ;
Park, Nam-Gyu ;
Kim, Junkyung ;
Lee, Hyunjung .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (07) :1093-1099
[19]   Inverse opal structure of nitrogen-doped titanium oxide with enhanced visible-light photocatalytic activity [J].
Li, Qi ;
Shang, Jian Ku .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (02) :660-663
[20]   Hydrogen generation from photoelectrochemical water splitting based on nanomaterials [J].
Li, Yat ;
Zhang, Jin Zhong .
LASER & PHOTONICS REVIEWS, 2010, 4 (04) :517-528