Programmable metal assembly on bio-inspired templates

被引：69
作者：
Tanaka, Kentaro [1 ]
Shionoya, Mitsuhiko [2 ]
机构：
[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
来源：
COORDINATION CHEMISTRY REVIEWS | 2007年 / 251卷 / 21-24期
关键词：
assembled metal complexes; DNA; self-assembly; template synthesis;
D O I：
10.1016/j.ccr.2007.08.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Besides the biological importance of DNA as genetic information storage and expression, DNA has great potential to act as a smart molecule for programmable self-assembly of functional units since it is possible to encode molecular assembled systems using sequences of nucleobases in a designable fashion. Recently, we have reported a novel base-pairing motif in DNA duplex that is based on the replacement of hydrogen-bonded base pairs by metal-mediated base pairs. This review covers our recent approaches to precise programming of metal arrays by means of artificial DNA templates. (C) 2007 Elsevier B.V. All rights reserved.
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收藏
页码：2732 / 2742
页数：11
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