A phenothiazine/dimesitylborane hybrid material as a bipolar transport host of red phosphor

被引:20
作者
Cheng, Yu-Jen [1 ,2 ]
Yu, Siao-Yin [3 ]
Lin, Song-Cheng [3 ]
Lin, Jiann T. [1 ]
Chen, Li-Yin [3 ]
Hsiu, Dai-Sin [2 ]
Wen, Yuh Sheng [1 ]
Lee, Mandy M. [1 ]
Sun, Shih-Sheng [1 ]
机构
[1] Acad Sinica, Inst Chem, Taipei 11529, Taiwan
[2] Natl Chung Cheng Univ, Dept Chem & Biochem, Chiayi 621, Taiwan
[3] Natl Sun Yat Sen Univ, Dept Photon, Kaohsiung 804, Taiwan
关键词
LIGHT-EMITTING-DIODES; EXTERNAL QUANTUM EFFICIENCY; AMORPHOUS MOLECULAR MATERIALS; CARRIER TRANSPORT; DELAYED FLUORESCENCE; SINGLE-LAYER; OPTICAL-ABSORPTION; ELECTRON-MOBILITY; TRIPLET ENERGY; BLUE;
D O I
10.1039/c6tc03335k
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
New bipolar transport compounds containing a meta-conjugated phenothiazine/dimesitylborane hybrid have been synthesized and three of them were characterized via single crystal structural determination. The compounds exhibited emission from blue to green, and one of them has a dual emission behavior. Organic light-emitting diodes using the compounds as the host for the red-emitting guest, Ir(pq)(2)(acac) (bis(2-phenylquinoline)(acetylacetonate) iridium), have external quantum efficiencies in the range of 6.3-15.5%. Some devices have a negligible efficiency roll-off up to 1000 cd m(-2).
引用
收藏
页码:9499 / 9508
页数:10
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