Recognition Properties of Cucurbit[7]uril Self-Assembled Monolayers Studied with Force Spectroscopy

被引：37

作者：

Gomez-Casado, Alberto ^{[1
]}

Jonkheijm, Pascal ^{[1
]}

Huskens, Jurriaan ^{[1
]}

机构：

[1] Univ Twente, Mol Nanofabricat Grp, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

来源：

LANGMUIR | 2011年 / 27卷 / 18期

关键词：

ORGANIC-MOLECULES; METAL-ION; HOST; CUCURBITURIL; CALIBRATION; INCLUSION; ADHESION; COMPLEX; BINDING;

D O I：

10.1021/la202346r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Specific (host guest) and unspecific (substrate guest) interactions, between self-assembled monolayers of cucurbit[7]uril (CB[7]) on gold, (Au) substrates and neutral adamantyl (Ad) guests were resolved by studying these, interactions at the single molecule level using dynamic force spectroscopy. The dissociation rate constants of the Ad-Au and the Ad-CB[7] interactions were 0.3 s(-1) and 0.03 s(-1), respectively, indicating that the specific binding is more stable. The probability of observing a specific interaction (40 +/- 9%) is similar to the reported surface coverages of CB[7] monolayers on Au substrates. The higher strength and stability of the Ad-CB[7] interactions explains why, although presenting an imperfect coverage, CB[n] monolayers can be used successfully as a platform for surface immobilization.

引用

页码：11508 / 11513

页数：6

共 50 条

[41] Recognition of 1,4-Xylylene Binding Sites in Polyimidazolium Cations by Cucurbit[7]uril: Toward Pseudorotaxane Assembly [J].

Samsam, Salim ;

Leclercq, Loic ;

Schmitzer, Andreea R. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (28) :9493-9498

[42] Metal-Assisted Complexation of Fluorogenic Dyes by Cucurbit[7]uril and Cucurbit[8]uril: A DFT Evaluation of the Key Factors Governing the Host-Guest Recognition [J].

Kircheva, Nikoleta ;

Dobrev, Stefan ;

Dasheva, Lyubima ;

Nikolova, Valya ;

Angelova, Silvia ;

Dudev, Todor .

MOLECULES, 2023, 28 (04)

[43] Effect of the Chain Length and Temperature on the Adhesive Properties of Alkanethiol Self-Assembled Monolayers [J].

Gojzewski, Hubert ;

Kappl, Michael ;

Ptak, Arkadiusz .

LANGMUIR, 2017, 33 (43) :11862-11868

[44] Cucurbit[7]uril-Based Vesicles Formed by Self-assembly of Supramolecular Amphiphiles [J].

Li Jiaxi ;

Zhou Lipeng ;

Luo Quan ;

Wang Yongguo ;

Zhang Chunqiu ;

Lu Wei ;

Xu Jiayun ;

Liu Junqiu .

CHINESE JOURNAL OF CHEMISTRY, 2012, 30 (09) :2085-2090

[45] The Effect of Cucurbit[7]uril on the Antitumor and Immunomodulating Properties of Oxaliplatin and Carboplatin [J].

Pashkina, Ekaterina ;

Aktanova, Alina ;

Mirzaeva, Irina ;

Kovalenko, Ekaterina ;

Andrienko, Irina ;

Knauer, Nadezhda ;

Pronkina, Natalya ;

Kozlov, Vladimir .

INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2021, 22 (14)

[46] Sequence, Structure, and Function of Peptide Self-Assembled Monolayers [J].

Nowinski, Ann K. ;

Sun, Fang ;

White, Andrew D. ;

Keefe, Andrew J. ;

Jiang, Shaoyi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (13) :6000-6005

[47] Comparison of Precursors for Self-Assembled Monolayers as Cu Barriers [J].

Cheng, Yi-Lung ;

Lee, Chih-Yen ;

Chen, Giin-Shan ;

Fang, Jau-Shiung .

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2023, 12 (06)

[48] Using self-assembled monolayers to model the extracellular matrix [J].

Mrksich, Milan .

ACTA BIOMATERIALIA, 2009, 5 (03) :832-841

[49] Degradation of self-assembled monolayers in organic photovoltaic devices [J].

Angel, Felipe A. ;

Lyubarskaya, Yekaterina L. ;

Shestopalov, Alexander A. ;

Tang, Ching W. .

ORGANIC ELECTRONICS, 2014, 15 (12) :3624-3631

[50] Nucleation Mechanisms of Self-Assembled Physisorbed Monolayers on Graphite [J].

Piskorz, Tomasz K. ;

Gobbo, Cristian ;

Marrink, Siewert J. ;

De Feyter, Steven ;

de Vries, Alex H. ;

van Esch, Jan H. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (28) :17510-17520

← 1 2 3 4 5 →