TiCl4/tert-butyl hydroperoxide:: Chemioselective oxidation of secondary alcohols and suppression of sharpless epoxidation

被引：5

作者：

Shei, Chun-Tin ^{[1
]}

Chien, Hao-Lun ^{[1
]}

Sung, Kuangsen ^{[1
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan

来源：

SYNLETT | 2008年 / 07期

关键词：

epoxidation; selective oxidation; alcohol;

D O I：

10.1055/s-2008-1066997

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Replacing Ti(Oi-Pr)(4) with TiCl(4) under the normal Sharpless epoxiation conditions resulted in a shut down of the epoxidation reaction. Instead, a chemioselective oxidation of secondary alcohols in the presence of primary alcohols occurred.

引用

页码：1021 / 1026

页数：6

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