Synthesis of poly-substituted benzenes starting from Baylis-Hillman adducts: DBU-assisted unusual dehydrogenation

被引：17
|
作者：
Kim, Seung Chan [1 ,2 ]
Lee, Ka Young [1 ,2 ]
Lee, Hyun Seung [1 ,2 ]
Kim, Jae Nyoung [1 ,2 ]
机构：
[1] Chonnam Natl Univ, Dept Chem, Kwangju 500757, South Korea
[2] Chonnam Natl Univ, Inst Basic Sci, Kwangju 500757, South Korea
来源：
TETRAHEDRON | 2008年 / 64卷 / 01期
关键词：
Baylis-hillman adducts; poly-substituted benzenes; DBU; dehydrogenation;
D O I：
10.1016/j.tet.2007.10.068
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Poly-substituted benzenes were synthesized in moderate yields starting from the Baylis-Hillman adducts. The synthesis was carried out by two steps via first synthesis of cyclohexene intermediates and the following DBU-assisted unusual dehydrogenation. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：103 / 109
页数：7
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