Giant Negative Electrocaloric Effects of Hf0.5Zr0.5O2 Thin Films

被引:116
作者
Park, Min Hyuk [1 ,2 ]
Kim, Han Joon [1 ,2 ]
Kim, Yu Jin [1 ,2 ]
Moon, Taehwan [1 ,2 ]
Do Kim, Keum [1 ,2 ]
Lee, Young Hwan [1 ,2 ]
Hyun, Seung Dam [1 ,2 ]
Hwang, Cheol Seong [1 ,2 ]
机构
[1] Seoul Natl Univ, Coll Engn, Dept Mat Sci & Engn, Seoul 151744, South Korea
[2] Seoul Natl Univ, Coll Engn, Interuniv Semicond Res Ctr, Seoul 151744, South Korea
基金
新加坡国家研究基金会;
关键词
PHASE; FIELD; FERROELECTRICITY; POLARIZATION;
D O I
10.1002/adma.201602787
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hafnia (HfO2)-zirconia (ZrO2) solid solution films show giant positive (Delta T = 13.4 K) and negative (Delta T = -10.8 K) electrocaloric effects that can be simply controlled by tuning the Hf/Zr ratio. It is expected that the combination of the electrocaloric effects with opposite signs in this lead-free, simple, binary oxide can significantly improve the efficiency of electrocaloric cooling.
引用
收藏
页码:7956 / 7961
页数:6
相关论文
共 42 条
[1]   Microscopic interpretation of sign reversal in the electrocaloric effect in a ferroelectric PbMg1/3Nb2/3O3-30PbTiO3 single crystal [J].
Axelsson, A. -K. ;
Le Goupil, F. ;
Dunne, L. J. ;
Manos, G. ;
Valant, M. ;
Alford, N. McN. .
APPLIED PHYSICS LETTERS, 2013, 102 (10)
[2]   Abnormal electrocaloric effect of Na0.5Bi0.5TiO3-BaTiO3 lead-free ferroelectric ceramics above room temperature [J].
Bai, Yang ;
Zheng, Guang-Ping ;
Shi, San-Qiang .
MATERIALS RESEARCH BULLETIN, 2011, 46 (11) :1866-1869
[3]   Giant electrocaloric effect in lead-free thin film of strontium bismuth tantalite [J].
Chen, Hao ;
Ren, Tian-Ling ;
Wu, Xiao-Ming ;
Yang, Yi ;
Liu, Li-Tian .
APPLIED PHYSICS LETTERS, 2009, 94 (18)
[4]   Identification of the ferroelectric switching process and dopant-dependent switching properties in orthorhombic HfO2: A first principles insight [J].
Clima, S. ;
Wouters, D. J. ;
Adelmann, C. ;
Schenk, T. ;
Schroeder, U. ;
Jurczak, M. ;
Pourtois, G. .
APPLIED PHYSICS LETTERS, 2014, 104 (09)
[5]   PST thin films for electrocaloric coolers [J].
Correia, T. M. ;
Kar-Narayan, S. ;
Young, J. S. ;
Scott, J. F. ;
Mathur, N. D. ;
Whatmore, R. W. ;
Zhang, Q. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2011, 44 (16)
[6]   Giant Negative Electrocaloric Effect in Antiferroelectric La-Doped Pb(ZrTi)O3 Thin Films Near Room Temperature [J].
Geng, Wenping ;
Liu, Yang ;
Meng, Xiangjian ;
Bellaiche, Laurent ;
Scott, James F. ;
Dkhil, Brahim ;
Jiang, Anquan .
ADVANCED MATERIALS, 2015, 27 (20) :3165-3169
[7]   Pathways towards ferroelectricity in hafnia [J].
Huan, Tran Doan ;
Sharma, Vinit ;
Rossetti, George A., Jr. ;
Ramprasad, Rampi .
PHYSICAL REVIEW B, 2014, 90 (06)
[8]   Electrocaloric effect based on the depolarization transition in (1-x)Bi0.5Na0.5TiO3-xKNbO3 lead-free ceramics [J].
Jiang, Xijie ;
Luo, Laihui ;
Wang, Baoyin ;
Li, Weiping ;
Chen, Hongbing .
CERAMICS INTERNATIONAL, 2014, 40 (02) :2627-2634
[9]   Inverse magnetocaloric effect in ferromagnetic Ni50Mn37+xSb13-x Heusler alloys [J].
Khan, Mahmud ;
Ali, Naushad ;
Stadler, Shane .
JOURNAL OF APPLIED PHYSICS, 2007, 101 (05)
[10]   A study on the wake-up effect of ferroelectric Hf0.5Zr0.5O2 films by pulse-switching measurement [J].
Kim, Han Joon ;
Park, Min Hyuk ;
Kim, Yu Jin ;
Lee, Young Hwan ;
Moon, Taehwan ;
Do Kim, Keum ;
Hyun, Seung Dam ;
Hwang, Cheol Seong .
NANOSCALE, 2016, 8 (03) :1383-1389