Growth and characterization of a new metal-organic crystal: potassium thiourea bromide

被引：140

作者：

Roshan, A ^{[1
]}

Joseph, C ^{[1
]}

Ittyachen, MA ^{[1
]}

机构：

[1] Mahatma Gandhi Univ, Crystal Phys Div, Sch Pure & Appl Phys, Kottayam 686560, Kerala, India

来源：

MATERIALS LETTERS | 2001年 / 49卷 / 05期

关键词：

crystal growth; nonlinear crystal; potassium thiourea bromide; X-ray diffraction; IR absorption studies;

D O I：

10.1016/S0167-577X(00)00388-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The growth and characterization of a new nonlinear metal-organic crystal, potassium thiourea bromide (PTB) is reported. The growth of single crystals of PTB was accomplished by slow evaporation method. The grown crystals were characterized by EDAX, X-ray powder diffraction and IR techniques. PTB crystallizes in tetragonal system and the complex formation is established by metal-sulfur bonds. PTB has good optical transmission in the entire visible region, which is an essential requirement for a nonlinear crystal. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：299 / 302

页数：4

共 14 条

[1] A new metal-organic crystal: Bismuth thiourea chloride [J].

Bhat, SG ;

Dharmaprakash, SM .

MATERIALS RESEARCH BULLETIN, 1998, 33 (06) :833-840

[2]

BHAT SG, 1997, J CRYST GROWTH, V81, P390

[3]

BORNSTEN L, 1982, NUMERICAL DATA FUNCT, V2, P584

[4] THE PREPARATION AND CHARACTERIZATION OF A NEW ORGANOMETALLIC NONLINEAR-OPTICAL MATERIAL - TRI-ALLYLTHIOUREA MERCURY BROMIDE (ATMB) CRYSTAL [J].

HOU, WB ;

JIANG, MH ;

RUAN, DR ;

XU, D ;

ZHANG, N ;

LIU, MG ;

TAO, XT .

MATERIALS RESEARCH BULLETIN, 1993, 28 (07) :645-653

[5] INVESTIGATIONS ON TRIALLYLTHIOUREA MERCURY BROMIDE (ATMB) CRYSTAL-GROWTH [J].

HOU, WB ;

XU, D ;

YUAN, DR ;

LIU, MG ;

ZHANG, N ;

TAO, XT ;

SUN, SY ;

JIANG, MH .

CRYSTAL RESEARCH AND TECHNOLOGY, 1994, 29 (07) :939-944

[6]

*JCPDS, 201488 JCPDS

[7]

Jiang M.H., 1985, SYNTH CRYST, V3-4, P1

[8]

Oussaid M, 1998, PHYS STATUS SOLIDI B, V207, P499, DOI 10.1002/(SICI)1521-3951(199806)207:2<499::AID-PSSB499>3.0.CO

[9]

2-L

[10] INFRA-RED ABSORPTION SPECTRA OF COMPLEXES OF THIOUREA [J].

SWAMINATHAN, K ;

IRVING, HMNH .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1964, 26 (07) :1291-1294

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