Vapor-Liquid Equilibrium in Diluted Polymer plus Solvent Systems

被引：8

作者：

Bogdanic, Grozdana ^{[1
]}

Wichterle, Ivan ^{[1
]}

机构：

[1] Acad Sci Czech Republic, Inst Chem Proc Fundamentals, Vvi, CR-16502 Prague 6, Czech Republic

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2011年 / 56卷 / 04期

关键词：

FLOW IMPROVER ADDITIVES; PREDICTION; MIXTURES; EQUATION;

D O I：

10.1021/je101052a

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapor-liquid equilibrium data were determined for five polymer + methylbenzene systems under isothermal conditions between (333.15 and 373.15) K. The polymers studied include copolymers and terpolymers of octadecyl propenoate, propenoic acid, ethenylbenzene, and 1-vinyl-2-pyrrolidone because of their practical importance as flow improvers for crude oil and/or derivatives. An all-glass microebulliometer with circulation of the liquid phase was used for measurements of total pressure over polymer + methylbenzene mixtures. Two predictive group-contribution models (entropic-free volume and group contribution-Flory) were applied to estimate the phase behaviors of two polymer solutions; good agreement with the experimental data was achieved.

引用

页码：1080 / 1083

页数：4

共 10 条

[1] PREDICTION OF VAPOR-LIQUID-EQUILIBRIA FOR MIXTURES WITH COPOLYMERS
BOGDANIC, G
FREDENSLUND, A
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (01) : 324 - 331
[2] REVISION OF THE GROUP-CONTRIBUTION FLORY EQUATION OF STATE FOR PHASE-EQUILIBRIA CALCULATIONS IN MIXTURES WITH POLYMERS .1. PREDICTION OF VAPOR-LIQUID-EQUILIBRIA FOR POLYMER-SOLUTIONS
BOGDANIC, G
FREDENSLUND, A
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1994, 33 (05) : 1331 - 1340
[3] Bondi A., 1968, PHYS PROPERTIES MOLE
[4] A NEW SIMPLE EQUATION FOR THE PREDICTION OF SOLVENT ACTIVITIES IN POLYMER-SOLUTIONS
ELBRO, HS
FREDENSLUND, A
RASMUSSEN, P
[J]. MACROMOLECULES, 1990, 23 (21) : 4707 - 4714
[5] Hansen H., 1992, SEP PUBLICATION, V9212
[6] Hao W., 1992, CHEM DATA SERIES 1, VXVI
[7] SIMPLE ACTIVITY-COEFFICIENT MODEL FOR THE PREDICTION OF SOLVENT ACTIVITIES IN POLYMER-SOLUTIONS
KONTOGEORGIS, GM
FREDENSLUND, A
TASSIOS, DP
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (02) : 362 - 372
[8] Studies on the influence of long chain acrylic esters polymers with polar monomers as crude oil flow improver additives
Kuzmic, Ana Erceg
Radosevic, Marko
Bogdanic, Grozdana
Srica, Vlasta
Vukovic, Radivoje
[J]. FUEL, 2008, 87 (13-14) : 2943 - 2950
[9] Flow improver additives for gas condensate
Kuzmic, Ana Erceg
Radosevic, Marko
Bogdanic, Grozdana
Vukovic, Radivoje
[J]. FUEL, 2007, 86 (10-11) : 1409 - 1416
[10] Circulation micro-ebulliometer for determination of pressure above mixtures containing solvent and non-volatile component
Pavlicek, Jan
Bogdanic, Grozdana
Wichterle, Ivan
[J]. FLUID PHASE EQUILIBRIA, 2010, 297 (01) : 142 - 148

← 1 →