Enamine-assisted facile generation of trifluoroacetaldehyde from trifluoroacetaldehyde ethyl hemiacetal and its carbon-carbon bond forming reaction leading to β-hydroxy-β-trifluoromethyl ketones

被引：33

作者：

Funabiki, K ^{[1
]}

Nojiri, M ^{[1
]}

Matsui, M ^{[1
]}

Shibata, K ^{[1
]}

机构：

[1] Gifu Univ, Fac Engn, Dept Chem, Gifu 5011193, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 18期

关键词：

D O I：

10.1039/a804922j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trifluoroacetaldehyde ethyl hemiacetal 1 readily reacts with various enamines 2 in hexane at room temperature for 1 h to give the corresponding beta-hydroxy-beta-trifluoromethyl ketones in good yields.

引用

页码：2051 / 2052

页数：2

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