A facile noncatalytic pathway for the nitrene transfer process: expeditious access to aziridines

被引：45
作者：
Saikia, Indranirekha [1 ]
Kashyap, Bishwapran [1 ]
Phukan, Prodeep [1 ]
机构：
[1] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期
关键词：
PORPHYRIN-CATALYZED AZIRIDINATION; NITROGEN-ATOM-TRANSFER; EFFICIENT AZIRIDINATION; BROMAMINE-T; BOND FORMATION; CHLORAMINE-T; N BOND; OLEFINS; ALKENES; AMIDATION;
D O I：
10.1039/c0cc05387b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A fast and efficient method has been developed for generation of sulfonyl nitrene from N,N-dibromo-p-toluenesulfonamide (TsNBr2) in the presence of a base without any catalyst. This method was applied to produce aziridines from different kinds of olefins within a short time in high yields.
引用
收藏
页码：2967 / 2969
页数：3
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