A facile noncatalytic pathway for the nitrene transfer process: expeditious access to aziridines

被引：45

作者：

Saikia, Indranirekha ^{[1
]}

Kashyap, Bishwapran ^{[1
]}

Phukan, Prodeep ^{[1
]}

机构：

[1] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 10期

关键词：

PORPHYRIN-CATALYZED AZIRIDINATION; NITROGEN-ATOM-TRANSFER; EFFICIENT AZIRIDINATION; BROMAMINE-T; BOND FORMATION; CHLORAMINE-T; N BOND; OLEFINS; ALKENES; AMIDATION;

D O I：

10.1039/c0cc05387b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fast and efficient method has been developed for generation of sulfonyl nitrene from N,N-dibromo-p-toluenesulfonamide (TsNBr2) in the presence of a base without any catalyst. This method was applied to produce aziridines from different kinds of olefins within a short time in high yields.

引用

页码：2967 / 2969

页数：3

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