Solid-state reactivity of copper(I) iodide: luminescent 2D-coordination polymers of CuI with saturated bidentate nitrogen bases

被引：76

作者：

Braga, Dario ^{[1
]}

Grepioni, Fabrizia ^{[1
]}

Maini, Lucia ^{[1
]}

Mazzeo, Paolo P. ^{[1
]}

Ventura, Barbara ^{[2
]}

机构：

[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[2] CNR, ISOF, I-40129 Bologna, Italy

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 02期

关键词：

TETRANUCLEAR; CLUSTERS; SOLVENT; PYRIDINE;

D O I：

10.1039/c0nj00547a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid-state reactions of copper(I) iodide with 1,4-diazabicyclo[2.2.2]octane (DABCO) and piperazine in different conditions (kneading, vapour digestion, thermal treatment) resulted in the formation of four new luminescent systems, which have been characterized via X-ray diffraction and photo-luminescence spectroscopy. At room temperature all compounds exhibit a bright emission in the solid state that markedly shifts bathochromically on cooling to 77 K. The luminescence of the almost isostructural 2D-coordination polymers [Cu2I2(L)(2)](infinity) (L = DABCO, piperazine) exhibits an unusually long lifetime (125 and 53 mu s, respectively), which becomes even longer (609 and 420 mu s, respectively) at 77 K.

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页码：339 / 344

页数：6

相关论文

共 34 条

[1] Photochemistry and photophysics of coordination compounds: Copper [J].

Armaroli, Nicola ;

Accorsi, Gianluca ;

Cardinali, Francois ;

Listorti, Andrea .

PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS I, 2007, 280 :69-115

[2] Questions for crystal engineering of halocuprate complexes: concepts for a difficult system [J].

Arnby, CH ;

Jagner, S ;

Dance, I .

CRYSTENGCOMM, 2004, 6 :257-275

[3] Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(I) [J].

Bai, Shi-Qiang ;

Kwang, Jia Yi ;

Koh, Lip Lin ;

Young, David J. ;

Hor, T. S. Andy .

DALTON TRANSACTIONS, 2010, 39 (10) :2631-2636

[4]

Braga D, 2007, J THERM ANAL CALORIM, V90, P115, DOI 10.1007/s10973-007-8484-y

[5] Simple and quantitative mechanochemical preparation of a porous crystalline material based on a 1D coordination network for uptake of small molecules [J].

Braga, D ;

Curzi, M ;

Johansson, A ;

Polito, M ;

Rubini, K ;

Grepioni, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) :142-146

[6] Reactions between or within molecular crystals [J].

Braga, D ;

Grepioni, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (31) :4002-4011

[7] Supramolecular complexation of alkali cations through mechanochemical reactions between crystalline solids [J].

Braga, D ;

Maini, L ;

Giaffreda, SL ;

Grepioni, F ;

Chierotti, MR ;

Gobetto, R .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (13) :3261-3269

[8] Solvent effect in a "solvent free" reaction [J].

Braga, Dario ;

Giaffreda, Stefano Luca ;

Grepioni, Fabrizia ;

Chierotti, Michele R. ;

Gobetto, Roberto ;

Palladino, Giuseppe ;

Polito, Marco .

CRYSTENGCOMM, 2007, 9 (10) :879-881

[9] Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo[2.2.2]octane) [J].

Braga, Dario ;

Maini, Lucia ;

Mazzeo, Paolo P. ;

Ventura, Barbara .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (05) :1553-1559

[10] Direct structure determination of a multicomponent molecular crystal prepared by a solid-state grinding procedure [J].

Cheung, EY ;

Kitchin, SJ ;

Harris, KDM ;

Imai, Y ;

Tajima, N ;

Kuroda, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (48) :14658-+

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