Solid-state reactivity of copper(I) iodide: luminescent 2D-coordination polymers of CuI with saturated bidentate nitrogen bases

被引：74
作者：
Braga, Dario [1 ]
Grepioni, Fabrizia [1 ]
Maini, Lucia [1 ]
Mazzeo, Paolo P. [1 ]
Ventura, Barbara [2 ]
机构：
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[2] CNR, ISOF, I-40129 Bologna, Italy
来源：
NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 02期
关键词：
TETRANUCLEAR; CLUSTERS; SOLVENT; PYRIDINE;
D O I：
10.1039/c0nj00547a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solid-state reactions of copper(I) iodide with 1,4-diazabicyclo[2.2.2]octane (DABCO) and piperazine in different conditions (kneading, vapour digestion, thermal treatment) resulted in the formation of four new luminescent systems, which have been characterized via X-ray diffraction and photo-luminescence spectroscopy. At room temperature all compounds exhibit a bright emission in the solid state that markedly shifts bathochromically on cooling to 77 K. The luminescence of the almost isostructural 2D-coordination polymers [Cu2I2(L)(2)](infinity) (L = DABCO, piperazine) exhibits an unusually long lifetime (125 and 53 mu s, respectively), which becomes even longer (609 and 420 mu s, respectively) at 77 K.
引用
收藏
页码：339 / 344
页数：6
相关论文
共 34 条
  • [1] Photochemistry and photophysics of coordination compounds: Copper
    Armaroli, Nicola
    Accorsi, Gianluca
    Cardinali, Francois
    Listorti, Andrea
    [J]. PHOTOCHEMISTRY AND PHOTOPHYSICS OF COORDINATION COMPOUNDS I, 2007, 280 : 69 - 115
  • [2] Questions for crystal engineering of halocuprate complexes: concepts for a difficult system
    Arnby, CH
    Jagner, S
    Dance, I
    [J]. CRYSTENGCOMM, 2004, 6 : 257 - 275
  • [3] Functionalized 1,2,3-triazoles as building blocks for photoluminescent POLOs (polymers of oligomers) of copper(I)
    Bai, Shi-Qiang
    Kwang, Jia Yi
    Koh, Lip Lin
    Young, David J.
    Hor, T. S. Andy
    [J]. DALTON TRANSACTIONS, 2010, 39 (10) : 2631 - 2636
  • [4] Braga D, 2007, J THERM ANAL CALORIM, V90, P115, DOI 10.1007/s10973-007-8484-y
  • [5] Simple and quantitative mechanochemical preparation of a porous crystalline material based on a 1D coordination network for uptake of small molecules
    Braga, D
    Curzi, M
    Johansson, A
    Polito, M
    Rubini, K
    Grepioni, F
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) : 142 - 146
  • [6] Reactions between or within molecular crystals
    Braga, D
    Grepioni, F
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (31) : 4002 - 4011
  • [7] Supramolecular complexation of alkali cations through mechanochemical reactions between crystalline solids
    Braga, D
    Maini, L
    Giaffreda, SL
    Grepioni, F
    Chierotti, MR
    Gobetto, R
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (13) : 3261 - 3269
  • [8] Solvent effect in a "solvent free" reaction
    Braga, Dario
    Giaffreda, Stefano Luca
    Grepioni, Fabrizia
    Chierotti, Michele R.
    Gobetto, Roberto
    Palladino, Giuseppe
    Polito, Marco
    [J]. CRYSTENGCOMM, 2007, 9 (10): : 879 - 881
  • [9] Reversible Interconversion between Luminescent Isomeric Metal-Organic Frameworks of [Cu4I4(DABCO)2] (DABCO=1,4-Diazabicyclo[2.2.2]octane)
    Braga, Dario
    Maini, Lucia
    Mazzeo, Paolo P.
    Ventura, Barbara
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (05) : 1553 - 1559
  • [10] Direct structure determination of a multicomponent molecular crystal prepared by a solid-state grinding procedure
    Cheung, EY
    Kitchin, SJ
    Harris, KDM
    Imai, Y
    Tajima, N
    Kuroda, R
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (48) : 14658 - +
1234