Electrosynthesis of poly(p-phenylene) and poly(p-phenylene/pyrrole) films under controlled humidity

被引：0

作者：

Eiras, Carla ^{[1
]}

Foschini, Mauricio ^{[2
]}

Soares, Juliana C. ^{[3
]}

Goncalves, Debora ^{[3
]}

机构：

[1] Univ Fed Piaui, Ctr Ciencias Nat, Teresina, PI, Brazil

[2] Univ Fed Uberlandia, Inst Fis, BR-38400 Uberlandia, MG, Brazil

[3] Univ Sao Paulo, Inst Fis Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

来源：

CHEMICAL PAPERS | 2015年 / 69卷 / 07期

基金：

巴西圣保罗研究基金会;

关键词：

conducting polymers; polypyrrole; conjugated polymers; copolymers; poly-p-phenylene; STRONG PROTON ACID; P-TERPHENYL; ELECTROPOLYMERIZATION; BIPHENYL; BENZENE; POLY(PARA-PHENYLENE); ELECTROCHEMISTRY; POLYPYRROLE; POLYMERS; WATER;

D O I：

10.1515/chempap-2015-0107

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(p-phenylene/pyrrole) (PPP-PPY) films were electrochemically synthesised on transparent ndium-till-oxide-covered glass (110) electrodes. The presence of two monomers, p-phenylene and pyrrole, Ill the polymerisation medium facilitated the synthesis process, yielding electroactive, uniform and stable films. In order to obtain materials with improved quality, PPP, PPY and PPP-PPY films were prepared in a mild, dry atmosphere. The morphological, electrochemical and optical properties were compared for different films obtained by varying the number of cycles with and without controlling humidity. (C) 2015 Institute of Chemistry, Slovak Academy of Sciences

引用

页码：958 / 963

页数：6

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