Hydrohalogenation reaction of electron-deficient allenes

被引：16

作者：

Ma, SM ^{[1
]}

Li, LT ^{[1
]}

Wei, Q ^{[1
]}

Xie, HX ^{[1
]}

Wang, GW ^{[1
]}

Shi, ZJ ^{[1
]}

Zhang, JL ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Organomet Chem Lab, Shanghai 200032, Peoples R China

来源：

PURE AND APPLIED CHEMISTRY | 2000年 / 72卷 / 09期

关键词：

D O I：

10.1351/pac200072091739

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrohalogenation reactions of electron-deficient allenes, such as 1,2-allenyl ketones, carboxylic acids, esters, amides, nitriles, sulfoxides, sulfones, and phosphine oxides with MX in HOAc, CF3COOH-HOAc, CF3COOH or AlCl3/H2O, afforded beta -halo-beta,gamma -unsaturated functionalized alkenes. The regioselectivity of the reaction could be controlled by the reaction conditions.

引用

页码：1739 / 1743

页数：5

共 18 条

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