Direct electrosynthesis of 52% concentrated CO on silver's twin boundary

The gaseous product concentration in direct electrochemical CO2 reduction is usually hurdled by the electrode's Faradaic efficiency, current density, and inevitable mixing with the unreacted CO2. A concentrated gaseous product with high purity will greatly lower the barrier for large-scale CO2 fixation and follow-up industrial usage. Here, we developed a pneumatic trough setup to collect the CO2 reduction product from a precisely engineered nanotwinned electrocatalyst, without using ion-exchange membrane. The silver catalyst's twin boundary density can be tuned from 0.3 to 1.5x10(4)cm(-1). With the lengthy and winding twin boundaries, this catalyst exhibits a Faradaic efficiency up to 92% at -1.0V and a turnover frequency of 127s(-1) in converting CO2 to CO. Through a tandem electrochemical-CVD system, we successfully produced CO with a volume percentage of up to 52%, and further transformed it into single layer graphene film. Isolating purified electrosynthesis product is a major challenge in electrochemical carbon dioxide reduction. Here, the authors report a nanotwinned silver electrocatalyst and a pneumatic-trough cell system to produce a 52% concentrated CO, which is further utilized as a carbon feedstock for graphene production.