Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

被引：42
作者：
Yang, Zheng [1 ,2 ]
Peng, Dongjie [1 ,2 ]
Du, Xiaoyong [1 ,2 ]
Huang, Zheng [1 ,2 ]
Ma, Shengming [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Fudan Univ, Dept Chem, 220 Handan Lu, Shanghai 200433, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2017年 / 4卷 / 09期
基金：
中国国家自然科学基金;
关键词：
REGIOSELECTIVE HYDROSILYLATION; IRON CATALYSTS; ALKENE HYDROSILYLATION; ORGANIC-SYNTHESIS; SILICON HYDRIDES; COMPLEXES; ALKYNES; PALLADIUM; ORGANOSILANES; OXIDATION;
D O I：
10.1039/c7qo00497d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient method of cobalt-catalyzed allene-hydrosilylation is developed. The reaction enjoys an excellent regio- and stereoselectivity and a broad scope affording Z-allylic silanes. Many synthetically useful functional groups can be tolerated. A Co(I)-species involved mechanism is proposed.
引用
收藏
页码：1829 / 1832
页数：4
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