Synthesis, spectroscopic characterization, and crystal structures of two chlorodiorganotin(IV) 4-(2-methoxyphenyl)piperazine-1-carbodithioates

被引：24

作者：

Zia-ur-Rehman ^{[1
,2
]}

Barsan, Mirela M. ^{[1
]}

Wharf, Ivor ^{[1
]}

Muhammad, Niaz ^{[2
]}

Ali, Saqib ^{[2
]}

Meetsma, Auke ^{[3
]}

Butler, Ian S. ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

[2] Quaid I Azam Univ, Dept Chem, Islamabad 45320, Pakistan

[3] Univ Groningen, Crystal Struct Ctr, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands

来源：

INORGANICA CHIMICA ACTA | 2008年 / 361卷 / 11期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Dithiocarboxylate; Chlorodiorganotin complexes; Raman; NMR; Mass spectra; X-ray diffraction;

D O I：

10.1016/j.ica.2008.05.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two chlorodiorganotin(IV) complexes of 4-(2-methoxyphenyl)piperazine-1-carbodithioate (MPPDA) have been synthesized by 1:1 mole-ratio reactions of the parent acid (MPPDAH) with Me2SnCl2 or Et2SnCl2 in dry methanol. The products have been characterized by Raman and multinuclear NMR (H-1, C-13 and Sn-119) spectroscopy, elemental analysis, and mass spectrometry. Single-crystal X-ray diffraction studies indicate that both complexes have distorted trigonal bipyramidal geometries around the central Sn atom. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：3322 / 3326

页数：5