[Bmmim]6[In10Se16Cl4]•(MIm)2: an organic-ligand free discrete T3 cluster for efficient hydrogen evolution under visible light irradiation

被引：8

作者：

Wang, Yanqi ^{[1
,2
]}

Hu, Qianqian ^{[2
]}

Jin, Jiance ^{[2
,3
]}

Li, Jilong ^{[2
]}

Li, Jianrong ^{[2
]}

Huang, Xiaoying ^{[2
]}

机构：

[1] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 16期

基金：

中国国家自然科学基金;

关键词：

INDIUM SULFIDE CLUSTERS; QUANTUM DOTS; WATER; H-2; SUPERTETRAHEDRON; NANOCRYSTALS; GENERATION; CATALYST; FUTURE; GROWTH;

D O I：

10.1039/d0dt00013b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An indium selenide [Bmmim](6)[In10Se16Cl4](MIm)(2) (Bmmim = 1-butyl-2,3-dimethylimidazolium, MIm = 1-methylimidazole) cluster has been synthesized and characterized. The discrete T3 cluster could be stably dispersed in dimethyl sulfoxide, exhibiting photocatalytic hydrogen evolution activity at least six times that of the pristine in the solid state due to the exposure of more active sites.

引用

页码：5020 / 5023

页数：4

共 6 条

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