Hydrothermal Synthesis, Characterization of Mn(II) and Cd(II) Coordination Polymers Assembled from Semi-Rigid Oxo-Bridged Carboxylate and N-Donor Ligands

被引：1

作者：

Yu, Ling-Ling ^{[1
]}

机构：

[1] Weihai Vocat Coll, Dept Biol Chem Engn, Weihai 264210, Shandong, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2012年 / 22卷 / 01期

关键词：

Hydrothermal synthesis; Coordination polymer; Manganese(II)/cadmium(II) complexes; ROOM-TEMPERATURE; POROUS MATERIAL; PHOTOLUMINESCENCE; BLUE; FRAMEWORKS;

D O I：

10.1007/s10904-011-9552-0

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Two new metal-organic coordination polymers containing Mn(II) and Cd(II) with oxo-bridged and N-donor ligands, [Mn(oba)(2,2'-bipy)](n) (1) and {[Cd(oba)(bib)]center dot H2O}(n) (2) [2,3'-H(2)oba = 2-(3-carboxyphenoxy)benzoic acid, 2,2'-bipy = 2,2'-bipyridine, and bib = 4,4'-bis(2-methyl imidazole-1-ylmethyl)biphenyl], have been prepared and characterized by elemental analysis, Fourier infrared spectroscopy, and X-ray diffraction. Complex 1 has a 3D supramolecular network constructed from 1D zigzag chain via pi-pi stacking interactions. Complex 2 features 1D ladder-like chain which consists of 1D helical arrays and bib pillars. Moreover, photoluminescence properties of the bib ligand and the Cd(II) complex were investigated.

引用

页码：278 / 282

页数：5

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