Coordination tailoring of water-labile 3D MOFs to fabricate ultrathin 2D MOF nanosheets

被引：45

作者：

Wen, Yuehong ^{[1
]}

Liu, Qiang ^{[1
,2
]}

Su, Shaodong ^{[1
]}

Yang, Yuying ^{[1
,2
]}

Li, Xiaofang ^{[1
]}

Zhu, Qi-Long ^{[1
]}

Wu, Xintao ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

NANOSCALE | 2020年 / 12卷 / 24期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; DESIGN; PHOTOLUMINESCENT; STABILITY; CARBON; MONS;

D O I：

10.1039/d0nr02956d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel coordination tailoring top-down delamination strategy involving the controllable partial disassembly of water-labile 3D MOFs has been explored to fabricate ultrathin 2D MOF nanosheets, and it exhibits many advantages such as green, convenience and high efficiency. Accordingly, 2D ultrathin MOF nanosheets with a two-fold interpenetrated architecture have been rapidly obtained from a 3D pillar-layered MOF, and they show distinguished fluorescence responses to different solvents.

引用

页码：12767 / 12772

页数：6

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