Synthesis and photoluminescence of the solid phases of the binary system of mixed-ligand Eu(III) and Tb(III) dithiophosphinate complexes

被引：0

作者：

Bryleva, Yu. A. ^{[1
]}

Rakhmanova, M. I. ^{[1
]}

Korol'kov, I. V. ^{[1
,2
]}

Tsygankova, A. R. ^{[1
,2
]}

Larionov, S. V. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 09期

关键词：

lanthanide; dithiophosphinate; complex; photoluminescence; DITHIOCARBAMATE COMPLEXES; COORDINATION POLYMERS; HIGHLY LUMINESCENT; ENERGY-TRANSFER; LANTHANIDE; EUROPIUM(III); FRAMEWORKS; TB; SM; LN;

D O I：

10.1134/S107036321609019X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid phases of the [Eu(Phen)(i-Bu2PS2)(2)(NO3)]-[Tb(Phen)(i-Bu2PS2)(2)(NO3)] binary system are synthesized. The results of X-ray diffraction phase analysis and photoluminescence measurements allow the synthesized isostructural phases to be classed with substitutional solid solutions. The photoluminescence measurements revealed Tb(III)-> Eu(III) energy transfer which induces Eu3+ luminescence.

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页码：2095 / 2099

页数：5

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