Synthesis and photoluminescence of the solid phases of the binary system of mixed-ligand Eu(III) and Tb(III) dithiophosphinate complexes

被引:0
作者
Bryleva, Yu. A. [1 ]
Rakhmanova, M. I. [1 ]
Korol'kov, I. V. [1 ,2 ]
Tsygankova, A. R. [1 ,2 ]
Larionov, S. V. [1 ,2 ]
机构
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Pr Akad Lavrenteva 3, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
关键词
lanthanide; dithiophosphinate; complex; photoluminescence; DITHIOCARBAMATE COMPLEXES; COORDINATION POLYMERS; HIGHLY LUMINESCENT; ENERGY-TRANSFER; LANTHANIDE; EUROPIUM(III); FRAMEWORKS; TB; SM; LN;
D O I
10.1134/S107036321609019X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solid phases of the [Eu(Phen)(i-Bu2PS2)(2)(NO3)]-[Tb(Phen)(i-Bu2PS2)(2)(NO3)] binary system are synthesized. The results of X-ray diffraction phase analysis and photoluminescence measurements allow the synthesized isostructural phases to be classed with substitutional solid solutions. The photoluminescence measurements revealed Tb(III)-> Eu(III) energy transfer which induces Eu3+ luminescence.
引用
收藏
页码:2095 / 2099
页数:5
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