Hydrothermal in situ ligand synthesis and chiral self-assembly with Pr(III)

被引:6
|
作者
Lin, Ling [1 ,2 ]
Zhang, Xin [1 ]
Zhang, Jian [1 ]
Yao, Yuan-Gen [1 ]
机构
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
Hydrolysis; C-O ether bond cleavage; Chiral self-assembly; Magnetic behavior; ELECTRON-TRANSFER; COMPLEXES; POLYMERS;
D O I
10.1016/j.molstruc.2011.07.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
P-4mo-BDCME (5-(pyridine-4-ylmethoxy)-isophthalic acid dimethyl ester) is undergoing hydrolysis, C-O ether bond cleavage and simultaneous self-assembly with Pr(III) to produce a new chiral compound, [Pr-2(HO-BDC)(3)(H2O)(2)] (1 HO-BDC = 5-hydroisophthalic acid), which features a three-dimensional (3D) framework with right-handed helices. Moreover, the magnetic behavior of 1 was investigated in the temperature range of 2-300 K. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:83 / 86
页数:4
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