Interfacial Structure at Ionic-liquid/Molecular-liquid Interfaces Probed by Sum-Frequency Generation Vibrational Spectroscopy

被引：0

作者：

Iwahashi, Takashi ^{[1
]}

Miyamae, Takayuki

Kanai, Kaname ^{[1
]}

Seki, Kazuhiko ^{[1
]}

Kim, Doseok

Ouchi, Yukio ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Nagoya, Aichi 4648601, Japan

来源：

IONIC LIQUIDS: FROM KNOWLEDGE TO APPLICATION | 2009年 / 1030卷

关键词：

TEMPERATURE MOLTEN-SALT; LITHIUM BATTERY ELECTROLYTE; MOLECULAR-DYNAMICS; DOUBLE-LAYER; ELECTROCHEMICAL PROPERTIES; NONPOLARIZED INTERFACE; AIR/LIQUID INTERFACE; AQUEOUS INTERFACES; NONLINEAR OPTICS; VAPOR INTERFACE;

D O I：

暂无

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

IR-visible sum frequency generation (SFG) vibrational spectroscopy was employed to investigate the microscopic structures at interfaces between room temperature ionic liquids and various molecular liquids. The alkyl chain of the [C(n)mim](+) polar cation orients toward the hydrophobic (CCl(4)) phase at the CCl(4)/ionic liquid interface, while it orients randomly or points towards the ionic liquid phase at a D(2)O/ionic liquid interface. An anomalous enhancement in the amplitude of the CD(3) asymmetric stretching mode is observed at a butanol/ionic liquid interface, suggesting the formation of a hydrophobic layer which consists of the alkyl chains of the butanol and the [C(n)mim](+) cation.

引用

页码：305 / 316

页数：12

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