Catalytic activity and antibacterial properties of nanopolymer-supported copper complex for C-N coupling reactions of amines and nitrogen-containing heterocycles with aryl halides

被引：9

作者：

Nasrollahzadeh, Mahmoud ^{[1
]}

Zahraei, Ali ^{[1
]}

Pourbasheer, Eslam ^{[1
]}

机构：

[1] PNU, Dept Chem, Tehran, Iran

来源：

MONATSHEFTE FUR CHEMIE | 2015年 / 146卷 / 08期

关键词：

Nanopolymer; Copper; Complex; Amine; Nitrogen-containing heterocycles; ROOM-TEMPERATURE; AEROBIC CONDITIONS; ARYLBORONIC ACIDS; GREEN SYNTHESIS; LIGAND-FREE; RECYCLABLE CATALYST; ARYLATION; WATER; NANOPARTICLES; AMINATION;

D O I：

10.1007/s00706-014-1367-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper reports on the antibacterial properties and application of nanopolymer-supported copper complex for the ligand-free C-N coupling reactions of amines and nitrogen-containing heterocycles with aryl halides. This method has the advantages of high yields, simple methodology, and easy workup. The catalyst can be recovered by simple filtration from the reaction mixture and reused several times without significant loss of catalytic activity. .

引用

收藏

页码：1329 / 1334

页数：6

相关论文

共 41 条

[1] Efficient Copper-Catalyzed N-Arylation of Amides and Imidazoles with Aryl Iodides [J].

Ali, Md. Ashif ;

Saha, Prasenjit ;

Punniyamurthy, Tharmalingam .

SYNTHESIS-STUTTGART, 2010, (06) :908-910

[2] 4,7-Dimethoxy-1,10-phenanthroline:: An excellent ligand for the Cu-catalyzed N-arylation of imidazoles [J].

Altman, Ryan A. ;

Buchwald, Stephen L. .

ORGANIC LETTERS, 2006, 8 (13) :2779-2782

[3]

[Anonymous], 1996, COMPREHENSIVE HETERO, DOI DOI 10.1016/B978-008096518-5.00109-X

[4] Copper-diamine-catalyzed N-arylation of pyrroles, pyrazoles, indazoles, imidazoles, and triazoles [J].

Antilla, JC ;

Baskin, JM ;

Barder, TE ;

Buchwald, SL .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (17) :5578-5587

[5] Practical copper-catalyzed N-arylation of nitrogen heterocycles with aryl halides under ligand and additive free conditions [J].

Chang, Joyce Wei Wei ;

Xu, Xiuhui ;

Chan, Philip Wai Hong .

TETRAHEDRON LETTERS, 2007, 48 (02) :245-248

[6] Ligand-free copper-catalyzed N-arylation of nitrogen nucleophiles [J].

Correa, Arkaitz ;

Bolm, Carsten .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (17-18) :2673-2676

[7]

Craig P.N., 1991, COMPREHENSIVE MED CH, V8

[8] Synthesis and characterization of copper nanoparticles supported on reduced graphene oxide as a highly active and recyclable catalyst for the synthesis of formamides and primary amines [J].

Fakhri, Parisa ;

Jaleh, Babak ;

Nasrollahzadeh, Mahmoud .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 383 :17-22

[9] P2O5-SiO2 as an efficient heterogeneous catalyst for the solvent-free synthesis of 1-substituted 1H-1,2,3,4-tetrazoles under conventional and ultrasound irradiation conditions [J].

Habibi, Davood ;

Nasrollahzadeh, Mahmoud ;

Mehrabi, Leila ;

Mostafaee, Samaneh .

MONATSHEFTE FUR CHEMIE, 2013, 144 (05) :725-728

[10] Ultrasound-promoted synthesis of novel 2-imino-3-aryl-2,3-dihydrobenzo[d]oxazol-5-ol 2-iminooxazolidines derivatives [J].

Habibi, Davood ;

Nasrollahzadeh, Mahmoud ;

Sahebekhtiari, Hesam ;

Parish, Richard Vernon .

TETRAHEDRON, 2013, 69 (14) :3082-3087

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