Novel fluorene-containing fullerenes C60:: synthesis and structures

被引：3

作者：

Gubskaya, V. P. ^{[1
]}

Nodov, K. L. ^{[1
]}

Sibgatullina, F. G. ^{[1
]}

Fazleeva, G. M. ^{[1
]}

Ismaev, I. E. ^{[1
]}

Latypov, Sh. K. ^{[1
]}

Efremov, Yu. Ya. ^{[1
]}

Nuretdinov, I. A. ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2007年 / 56卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

fullerene C-60; fluorene-2-carbaldehyde; 2,7-diacetylfluorene; spiromethano-fullerenes; fullerenopyrrolidine; homo; and heterocorrelation NMR spectroscopy; MALDI TOF mass spectrometry;

D O I：

10.1007/s11172-007-0286-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of fullerene C-60 with fluorene-2-carbaldehyde or 2,7-diacetylfluorene in toluene gave novel spiromethanofullerenes containing a reactive free formyl group. A novel fluorene-containing fullerenopyrrolidine was obtained by the Prato reaction. The purity and compositions of the compounds obtained were confirmed by MALDI TOF mass spectrometry and HPLC. Their structures were confirmed by 2D homo-and heterocorrelation NMR techniques.

引用

页码：1843 / 1848

页数：6

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