Catalytic Reforming: Methodology and Process Development for a Constant Optimisation and Performance Enhancement

被引:16
作者
Avenier, Priscilla [1 ]
Bazer-Bachi, Delphine [1 ]
Bazer-Bachi, Frederic [1 ]
Chizallet, Celine [1 ]
Deleau, Fabrice [1 ]
Diehl, Fabrice [1 ]
Gornay, Julien [1 ]
Lemaire, Eric [1 ]
Moizan-Basle, Virginie [1 ]
Plais, Cecile [1 ]
Raybaud, Pascal [1 ]
Richard, Florence [1 ]
Lacombe, Sylvie [1 ]
机构
[1] IFP Energies Nouvelles, Rond Point Echangeur Solaize,BP 3, F-69360 Solaize, France
来源
OIL & GAS SCIENCE AND TECHNOLOGY-REVUE D IFP ENERGIES NOUVELLES | 2016年 / 71卷 / 03期
关键词
GAMMA-ALUMINA; HYDROGEN CHEMISORPTION; PLATINUM NANOCLUSTERS; METAL-CATALYSTS; PARTICLE-SIZE; SUPPORT; KINETICS; INSIGHTS; INDIUM; SITES;
D O I
10.2516/ogst/2015040
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Catalytic reforming process has been used to produce high octane gasoline since the 1940s. It would appear to be an old process that is well established and for which nothing new could be done. It is however not the case and constant improvements are proposed at IFP Energies nouvelles. With a global R&D approach using new concepts and forefront methodology, IFPEN is able to: - propose a patented new reactor concept, increasing capacity; - ensure efficiency and safety of mechanical design for reactor using modelization of the structure; - develop new catalysts to increase process performance due to a high comprehension of catalytic mechanism by using, an experimental and innovative analytical approach (Sn-119 Mossbauer and X-ray absorption spectroscopies) and also a Density Functional Theory (DFT) calculations; - have efficient, reliable and adapted pilots to validate catalyst performance.
引用
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页数:17
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[1]  
Abolhamd G., 1980, THESIS
[2]   Long-Term Deactivation of Supported Pt Catalysts in the Dehydrogenation of Methylcyclohexane to Toluene [J].
Alhumaidan, Faisal ;
Cresswell, David ;
Garforth, Arthur .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (20) :9764-9770
[3]  
Antos G., 2004, CATALYTIC NAPHTHA RE
[4]   PT/AL2O3-CL IN PURE HYDROCARBON REFORMING [J].
BELTRAMINI, JN ;
MARTINELLI, EE ;
CHURIN, EJ ;
FIGOLI, NS ;
PARERA, JM .
APPLIED CATALYSIS, 1983, 7 (01) :43-55
[5]   ENVIRONMENT OF PLATINUM ATOMS IN A H2 PTCL6/AL2O3 CATALYST - INFLUENCE OF METAL LOADING AND CHLORINE CONTENT [J].
BERDALA, J ;
FREUND, E ;
LYNCH, JP .
JOURNAL DE PHYSIQUE, 1986, 47 (C-8) :269-272
[6]   INSITU CHARACTERIZATION OF HETEROGENEOUS CATALYSTS BY MOSSBAUER-SPECTROSCOPY [J].
BERRY, FJ ;
JOBSON, S ;
ZHANG, T ;
MARCO, JF .
CATALYSIS TODAY, 1991, 9 (1-2) :137-143
[7]  
Bertho Y., 2003, THESIS
[8]   Kinetics of alkane reactions on metal catalysts: activation energies and the compensation effect [J].
Bond, GC .
CATALYSIS TODAY, 1999, 49 (1-3) :41-48
[9]   Alkane transformations on supported platinum catalysts .4. Kinetics of hydrogenolysis of ethane, propane, and n-butane on Pt/Al2O3 (EUROPT-3) and PtRe/Al2O3 (EUROPT-4) [J].
Bond, GC ;
Cunningham, RH .
JOURNAL OF CATALYSIS, 1997, 166 (02) :172-185
[10]   Analysis of in situ EXAFS data of supported metal catalysts using the third and fourth cumulant [J].
Bus, Eveline ;
Miller, Jeffrey T. ;
Kropf, A. Jeremy ;
Prins, Roel ;
van Bokhoven, Jeroen A. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (27) :3248-3258