Diaquabis[5-(1H-tetrazol-5-ylamino-κN4)-1H-tetrazolato-κN1]iron(II) dihydrate

被引：12

作者：

Guan, Yang-Fan ^{[1
]}

Wang, Dong-Yao ^{[1
]}

Dong, Wen ^{[1
]}

机构：

[1] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510006, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807058448

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The centrosymmetric title complex, [Fe(C2H2N9)(2)(H2O)(2)]center dot 2H(2)O, has been prepared by an in situ [2+3] cycloaddition reaction of dicyanamide with sodium azide and ferrous sulfate, with heating and stirring. The FeII ion is coordinated by four N atoms from two 5-(1H-tetrazol-5-ylamino)-1H-tetrazolate ligands and two water molecules in axial positions in an octahedral geometry. The complex is linked into a three-dimensional network by O - H center dot center dot center dot N, N - H center dot center dot center dot O and N H center dot center dot center dot N hydrogen bonds.

引用

页码：M3150 / U2611

页数：9