Rhodium(III) and iridium(III) complexes of thioarylazoimidazoles Synthesis, structure, spectral characterization, electrochemistry and DFT calculation

被引：12
作者：
Sardar, Dibakar [1 ]
Datta, Papia [1 ]
Mitra, Partha [2 ]
Sinha, Chittaranjan [1 ]
机构：
[1] Jadavpur Univ, Dept Chem, Kolkata 700032, India
[2] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, India
来源：
POLYHEDRON | 2010年 / 29卷 / 17期
关键词：
Rh(III) and Ir(III) complexes; X ray structure; Electrochemistry; DFT and TDDFT computation; RAY CRYSTAL-STRUCTURES; EXCITATION-ENERGIES; ISOMERIC DICHLORO; ARYLAZOIMIDAZOLE; RUTHENIUM; LIGANDS; APPROXIMATION; AZOIMIDAZOLES; SENSITIZERS; CHEMISTRY;
D O I：
10.1016/j.poly.2010.08.038
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[M(SRaaiNR)Cl-3] (M = Rh(III) Ir(III) and SRaaiNR = 1 alkyl-2-((o-thioalkyl)phenylazo)imidazole) complexes are described in this article The single crystal X ray structure of one of the complexes [Rh(SMeaaiNEt)Cl-3] (3b) shows a tridentate chelation of SMeaaiNEt via N(imidazole) N(azo) and S(thioether) donor centres Spectral characterization has been done by IR UV-Vis and H-1 NMR data The electronic structure redox properties and spectra are well supported by DFT and TDDFT computation on the complexes (C) 2010 Elsevier Ltd All rights reserved
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页码：3170 / 3177
页数：8
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