Bis(2-aminopyridine-κN1)bis(benzoato-κ2O,O′)cadmium(II)

被引:4
作者
Zhong, Di-Chang [1 ]
Guo, Gui-Quan
Deng, Ji-Hua
Zhu, Rong-Hua
Zhou, Yi-Bin
机构
[1] Yichun Univ, Inst Coordinat Catalysis, Yichun 336000, Peoples R China
[2] Anyang Normal Univ, Coll Chem & Chem Engn, Anyang 455000, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807059181
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Cd(C7H5O2)(2)(C5H6N2)(2)], the Cd-II atom is hexacoordinated by four O atoms from two crystallographically independent benzoate anions, and two pyridine N atoms from two crystallographically independent 2-aminopyridine molecules in a distorted octahedral geometry. In the crystal structure, the metal complexes are connected by N-H center dot center dot center dot O hydrogen bonding between the carboxylate O atoms of the benzoate anions and the amino H atoms of the 2-aminopyridine ligands. The benzoate and the aminopyridine rings are stacked in the direction of the crystallographic a axis, indicating pi-pi stacking interactions are present [centroid-centroid distance = 3.6790 (15) angstrom
引用
收藏
页码:M3091 / U2098
页数:12
相关论文
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